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114596

N,N-Diphenylhydrazine hydrochloride

Name: <I>N</I>,<I>N</I>-Diphenylhydrazine hydrochloride
Brand: ALDRICH

97%

Synonym(s):

N,N-Diphenylhydrazine hydrochloride (asym.)

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About This Item

Linear Formula:

(C₆H₅)₂NNH₂ · HCl

CAS Number:

530-47-2

Molecular Weight:

220.70

Beilstein:

3569340

EC Number:

208-481-0

MDL number:

MFCD00012950

UNSPSC Code:

12352100

PubChem Substance ID:

24847185

NACRES:

NA.22

Assay

97%

form

solid

SMILES string

Cl.NN(c1ccccc1)c2ccccc2

InChI

1S/C12H12N2.ClH/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10H,13H2;1H

InChI key

MIVUDWFNUOXEJM-UHFFFAOYSA-N

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Related Categories

Organic Building Blocks

Application

N,N-Diphenylhydrazine hydrochloride is used in the synthesis of 2-Vinyloxyethyloxy-4-diethylaminophenyl-1-carbaldehyde N,N-diphenylhydrazone (hole-transporting hydrazine).

Other Notes

Small amounts of moisture cause melting point to vary greatly

Pictograms

GHS05,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H302,H314,H410

Precautionary Statements

P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Reduction of N-nitrosodiphenylamine to the corresponding hydrazine by guinea pig liver preparations.

K Tatsumi et al.

Chemical & pharmaceutical bulletin, 30(10), 3842-3845 (1982-10-01)

New reactive hole-transporting hydrazone and its adducts with diol and dithiol.

Journal of Optoelectronics and Advanced Materials, 8(4), 1533-1533 (2006)

Formation of N-nitrosodiphenylamine from 1,1-diphenylhydrazine by rat liver microsomal preparations.

K Tatsumi et al.

Biochemical and biophysical research communications, 118(3), 958-963 (1984-02-14)

The present study provides the first evidence for in vitro metabolic conversion of a 1,1-disubstituted hydrazine to the corresponding nitrosamine. The study shows that superoxide radical which is generated by NADPH-cytochrome c reductase is involved in the oxidation of 1,1-diphenylhydrazine

Synthesis of Ag(I) camphor sulphonylimine complexes and assessment of their cytotoxic properties against cisplatin-resistant A2780cisR and A2780 cell lines.

João M S Cardoso et al.

Journal of inorganic biochemistry, 166, 55-63 (2016-11-12)

Camphorsulphonylimine complexes [Ag(NO

Push-Pull N,N-Diphenylhydrazones Bearing Bithiophene or Thienothiophene Spacers as Nonlinear Optical Second Harmonic Generators and as Photosensitizers for Nanocrystalline TiO2 Dye-Sensitized Solar Cells.

Sara S M Fernandes et al.

ACS omega, 3(10), 12893-12904 (2018-11-10)

A series of push-pull heterocyclic N,N-diphenylhydrazones were prepared to study the effect of structural modifications (different π-spacers and electron-withdrawing groups) on the optical (linear and nonlinear) and electronic properties of the molecules. The photovoltaic response of dye-sensitized solar cells assembled

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