111279
4-Penten-1-ol
99%
Synonym(s):
2-Allylethyl alcohol
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About This Item
Linear Formula:
CH2=CH(CH2)3OH
CAS Number:
Molecular Weight:
86.13
Beilstein:
1560163
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39020310
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
99%
refractive index
n20/D 1.429 (lit.)
bp
134-137 °C (lit.)
density
0.834 g/mL at 25 °C (lit.)
SMILES string
OCCCC=C
InChI
1S/C5H10O/c1-2-3-4-5-6/h2,6H,1,3-5H2
InChI key
LQAVWYMTUMSFBE-UHFFFAOYSA-N
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General description
4-penten-1-ol forms ester bond at the C terminus of the linear peptide in solution with HATU as coupling agent.
Application
4-Penten-1-ol can be used as a reactant to prepare sulfamate ester by reacting with chlorosulfonyl isocycanate (142662).The derived ester undergoes an enantioselective intramolecular azridination reaction in the presence of Cu catalyst. 4-Penten-1-ol can also be used to study the epoxidation of olefins with oxo-diperoxo tungstate(VI) complex as catalyst and bicarbonate as co-catalyst.
Signal Word
Warning
Hazard Statements
Hazard Classifications
Flam. Liq. 3
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst.
Maiti SK, et al.
New. J. Chem., 30(3), 479-489 (2006)
Enantioselective Intramolecular Copper-Catalyzed Aziridination of Sulfamates
Audrey Esteoule.et al.
Synthesis, 1251-1251 (2007)
Marina D Rvovic et al.
Journal of molecular modeling, 17(6), 1251-1257 (2010-08-17)
The mechanism of phenylselenoetherification of pent-4-en-1-ol using some bases (pyridine, triethylamine, quinoline, 2,2'-bipyridine) as catalyst was examined through studies of kinetics of the cyclization, by UV-VIS spectrophotometry. It was demonstrated that the intramolecular cyclization is facilitated in the presence of
Stefania Terracciano et al.
Bioorganic & medicinal chemistry, 16(13), 6580-6588 (2008-05-30)
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