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10896

Sigma-Aldrich

Vinyl laurate

produced by Wacker Chemie AG, Burghausen, Germany, ≥98% (GC)

Synonym(s):

VL

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About This Item

Linear Formula:
CH3(CH2)10COOCH=CH2
CAS Number:
Molecular Weight:
226.36
Beilstein:
1778369
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

produced by Wacker Chemie AG, Burghausen, Germany

Quality Level

Assay

≥98% (GC)

bp

254 °C/1013 hPa (lit.)

solubility

H2O: slightly soluble 1 g/L at 20 °C

density

0.871 g/mL at 20 °C (lit.)

SMILES string

CCCCCCCCCCCC(=O)OC=C

InChI

1S/C14H26O2/c1-3-5-6-7-8-9-10-11-12-13-14(15)16-4-2/h4H,2-3,5-13H2,1H3

InChI key

GLVVKKSPKXTQRB-UHFFFAOYSA-N

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General description

Vinyl laurate is a clear, colorless to light yellow colored liquid. The flash point is 125°C. It forms aqueous colloidal microgel by copolymerization with N-isopropylacrylamide. The enzymatic acylation of Avicel cellulose with vinyl laurate, a solvent free reaction system, was studied.

Application

Vinyl laurate was used in the synthesis of laurate and stearate esters of corn starch. It was used as the acyl donor during synthesis of sucrose laurate esters catalyzed by Bacillus pseudofirmus AL-89 . Vinyl laurate was also used in the preparation of chirally deuterated benzyl chlorides.

Other Notes

prices for bulk quantities on request

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants.
Junistia L, et al.
Starch/Staerke, 60(12), 667-675 (2008)
Novel gelling behavior of poly (N-isopropylacrylamide-co-vinyl laurate) microgel dispersions.
Benee LS, et al.
Langmuir, 18(16), 6025-6030 (2002)
Synthesis of sucrose laurate using a new alkaline protease.
Pedersen NR, et al.
Tetrahedron Asymmetry, 14(6), 667-673 (2003)
Stavros Gremos et al.
Bioresource technology, 102(2), 1378-1382 (2010-10-05)
Cellulose esters are an important class of functional biopolymers with great interest in the chemical industry. In this work the enzymatic acylation of Avicel cellulose with vinyl propionate, vinyl laurate and vinyl stearate, has been performed successfully in a solvent
R U Trappe et al.
American journal of transplantation : official journal of the American Society of Transplantation and the American Society of Transplant Surgeons, 15(4), 1091-1100 (2015-03-05)
Tailoring treatment by patient strata based on the risk of disease progression and treatment toxicity might improve outcomes of patients with posttransplant lymphoproliferative disorder (PTLD). We analysed the cohort of 70 patients treated in the international, multicenter phase II PTLD-1

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