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Merck
CN

104744

Trimethoxyphenylsilane

97%

Synonym(s):

(Trimethoxysilyl)benzene, Phenyltrimethoxysilane

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About This Item

Linear Formula:
C6H5Si(OCH3)3
CAS Number:
Molecular Weight:
198.29
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
221-066-9
Beilstein/REAXYS Number:
2937896
MDL number:
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Product Name

Trimethoxyphenylsilane, 97%

InChI key

ZNOCGWVLWPVKAO-UHFFFAOYSA-N

InChI

1S/C9H14O3Si/c1-10-13(11-2,12-3)9-7-5-4-6-8-9/h4-8H,1-3H3

SMILES string

CO[Si](OC)(OC)c1ccccc1

assay

97%

form

liquid

refractive index

n20/D 1.468 (lit.)

bp

233 °C (lit.)

density

1.062 g/mL at 25 °C (lit.)

Quality Level

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Application

TMPS can also be used in the preparation of polytrimethoxyphenylsilane (PTMS) that facilitates the removal of graphene after chemical vapor deposition (CVD). Molecularly imprinted sol gels can be synthesized by using TMPS for the fabrication of localized surface plasmon resonance (LSPR).

General description

Trimethoxyphenylsilane (TMPS) is an organotrialkoxysilane that is used as a functional monomer in the sol-gel processing.

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3 - STOT RE 2 Oral

target_organs

Bladder

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Ti-POSS covalently immobilized onto mesoporous silica: A model for active sites in heterogeneous catalytic epoxidation
Carniato, F., Bisio, C., Sordelli, L., Gavrilova, E., & Guidotti, M.
Inorgorganica Chimica Acta, 380, 244-251 (2012)
Synthesis of hexa aza cages, SarAr-NCS and AmBaSar and a study of their metal complexation, conjugation to nanomaterials and proteins for application in radioimaging and therapy
Mume, Eskender, et al.
Dalton Transactions, 42(40), 14402-14410 (2013)
Bio-inspired molecularly imprinted polymer-green emitting carbon dot composite for selective and sensitive detection of 3-nitrotyrosine as a biomarker
Jalili R and Amjadi M
Sensors and Actuators B, Chemical, 255, 1072-1078 (2018)
Capillary microextraction of volatiles device for enhanced BTEX vapors sampling based on a phenyl modified PDMS sol-gel adsorption phase
Gura S, et al.
Analytica Chimica Acta, 1014, 27-40 (2018)
Xiaomei Yang et al.
Materials (Basel, Switzerland), 12(12) (2019-06-20)
In this work, we reported the preparation and chemical analysis of novel polyhedral oligomeric silsesquioxane (POSS)-based porous materials, which were prepared according to Friedel-Crafts chloromethylation by using aluminum chloride as the catalyst and dichloromethane as the solvent. Through controlling the

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