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Merck
CN

215155

Hydrazine

anhydrous, 98%

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About This Item

Linear Formula:
NH2NH2
CAS Number:
302-01-2
Molecular Weight:
32.05
NACRES:
NA.21
PubChem Substance ID:
24852873
UNSPSC Code:
12352300
EC Number:
206-114-9
MDL number:
MFCD00011417
Assay:
98%
Grade:
anhydrous
Form:
liquid

Key Documents

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Product Name

Hydrazine, anhydrous, 98%

InChI key

OAKJQQAXSVQMHS-UHFFFAOYSA-N

InChI

1S/H4N2/c1-2/h1-2H2

SMILES string

NN

grade

anhydrous

vapor density

1 (37 °C, vs air)

vapor pressure

10 mmHg ( 30.7 °C)

assay

98%

form

liquid

expl. lim.

99.99 %

refractive index

n20/D 1.47 (lit.)

bp

113.5 °C (lit.)

mp

1.4 °C (lit.)

density

1.021 g/mL at 25 °C (lit.)

Quality Level

200

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Application

Hydrazine has been used as one of the reaction components in the synthesis of a soluble chalcogenidometallate cluster salt, which is a precursor for the preparation of SnSe2.
Hydrazine may be used in the synthesis of:
  • pyridyl aminated O-linked sugar chains from glycoproteins
  • nanocomposite of manganese oxide embedded in graphene sheets (GS–Mn3O4)
  • formyl hydrazine by reacting with ethyl formate

General description

Hydrazine is the simplest diamine mainly used as a reducing agent.
Sensitive determination of hydrazine with detection limit of 10.0nM has been achieved by employing an electrochemical sensor. Hydrazine undergoes dehydrogenation in the presence of bimetallic NiRh nanoparticles (NPs) supported on nitrogen-doped porous carbon (NPC) derived from metal-organic frameworks (ZIF-8) to afford hydrogen.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ1451
MKCZ1452
MKCX4344
MKCX3529
MKCX0129

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NiRh nanoparticles supported on nitrogen-doped porous carbon as highly efficient catalysts for dehydrogenation of hydrazine in alkaline solution.
Xia B, et al.
Nano Research, 8(11), 3472-3479 (2015)
Rapid microwave-assisted synthesis of Mn 3 O 4?graphene nanocomposite and its lithium storage properties
Li L, et al.
Journal of Materials Chemistry, 22(8), 3600-3605 (2012)
Release of O-linked sugar chains from glycoproteins with anhydrous hydrazine and pyridylamination of the sugar chains with improved reaction conditions.
Kuraya N and Hase S.
Journal of Biochemistry, 112(1), 122-126 (1992)
Hadi Mahmoudi Moghaddam et al.
Environmental monitoring and assessment, 187(7), 407-407 (2015-06-06)
Hydrazine and phenol are two important environmental pollutants. In this work, an electrochemical sensor for the selective and sensitive detection of hydrazine in presence of phenol was developed by the bulk modification of carbon paste electrode (CPE) with TiO2 nanoparticles
Yoriko Nonomura et al.
Scientific reports, 9(1), 1551-1551 (2019-02-09)
Membrane proteins (such as ion channels, transporters, and receptors) and secreted proteins are essential for cellular activities. N-linked glycosylation is involved in stability and function of these proteins and occurs at Asn residues. In several organs, profiles of N-glycans have
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