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215155

Sigma-Aldrich

Hydrazine

anhydrous, 98%

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Linear Formula:
NH2NH2
CAS Number:
302-01-2
Molecular Weight:
32.05
EC Number:
206-114-9
MDL number:
MFCD00011417
UNSPSC Code:
12352300
PubChem Substance ID:
24852873
NACRES:
NA.21

grade

anhydrous

Quality Level

200

vapor density

1 (37 °C, vs air)

vapor pressure

10 mmHg ( 30.7 °C)

Assay

98%

form

liquid

expl. lim.

99.99 %

refractive index

n20/D 1.47 (lit.)

bp

113.5 °C (lit.)

mp

1.4 °C (lit.)

density

1.021 g/mL at 25 °C (lit.)

SMILES string

NN

InChI

1S/H4N2/c1-2/h1-2H2

InChI key

OAKJQQAXSVQMHS-UHFFFAOYSA-N

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General description

Hydrazine is the simplest diamine mainly used as a reducing agent.
Sensitive determination of hydrazine with detection limit of 10.0nM has been achieved by employing an electrochemical sensor. Hydrazine undergoes dehydrogenation in the presence of bimetallic NiRh nanoparticles (NPs) supported on nitrogen-doped porous carbon (NPC) derived from metal-organic frameworks (ZIF-8) to afford hydrogen.

Application

Hydrazine has been used as one of the reaction components in the synthesis of a soluble chalcogenidometallate cluster salt, which is a precursor for the preparation of SnSe2.
Hydrazine may be used in the synthesis of:
  • pyridyl aminated O-linked sugar chains from glycoproteins
  • nanocomposite of manganese oxide embedded in graphene sheets (GS–Mn3O4)
  • formyl hydrazine by reacting with ethyl formate

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Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Rapid microwave-assisted synthesis of Mn 3 O 4?graphene nanocomposite and its lithium storage properties
Li L, et al.
Journal of Materials Chemistry, 22(8), 3600-3605 (2012)
NiRh nanoparticles supported on nitrogen-doped porous carbon as highly efficient catalysts for dehydrogenation of hydrazine in alkaline solution.
Xia B, et al.
Nano Research, 8(11), 3472-3479 (2015)
The 3-methyl-2-benzothiazolone hydrazone test. Sensitive new methods for the detection, rapid estimation, and determination of aliphatic aldehydes.
Sawicki E, et al.
Analytical Chemistry, 33(1), 93-96 (1961)
Electronic and optical switching of solution-phase deposited SnSe2 phase change memory material.
Wang RY, et al.
Journal of Applied Physics, 109(11), 113506-113506 (2011)
Hydrazine as a reducing agent for organic compounds (catalytic hydrazine reductions).
Furst A, et al.
Chemical Reviews, 65(1), 51-68 (1965)
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