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Merck
CN

931217

Sigma-Aldrich

[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)

Umicore

别名:

Pd(dppf)Cl2

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About This Item

线性分子式:
(C17H14P)2Fe · PdCl2
CAS号:
分子量:
731.70
MDL编号:
UNSPSC代码:
12352103
NACRES:
NA.21

质量水平

形式

powder

mp

266-283 °C (lit.)

储存温度

2-8°C

SMILES字符串

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

JCWIWBWXCVGEAN-UHFFFAOYSA-L

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应用

CX93 is a catalyst for C-C and C-N coupling reaction. Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:-
  • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
  • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
  • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
For small scale and high throughput uses, product is also available as ChemBeads (919780)

储存及稳定性

Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

法律信息

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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