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Merck
CN
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文件

747769

Sigma-Aldrich

[Ir(dtbbpy)(ppy)2]PF6

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别名:
[Ir(dtbbpy)(ppy)2][PF6], [4,4′-双(1,1-二甲基乙基)-2,2′-联吡啶-N1,N1′]双[2-(2-吡啶基-N)苯基-C]铱(III)六氟磷酸盐, 铱光催化剂
经验公式（希尔记法）:
C40H40F6IrN4P
CAS号:
676525-77-2
分子量:
913.95
UNSPSC代码:
12161600
NACRES:
NA.22

形式

powder

质量水平

100

反应适用性

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

光触媒活化

455 nm

储存温度

2-8°C

SMILES字符串

CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F

InChI

1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;

InChI key

DZARMRZNOUWGQE-UHFFFAOYSA-N

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应用

[Ir(dtbbpy)(ppy)2]PF6 是一种铱类光催化剂，被用于催化各种光化学反应，如：
  • 通过氧化氮杂-亨利反应，催化 N-芳基胺与硝基烷烃的偶联。
  • 卤代烷烃通过原子转移自由基加成（ATRA）转化为烯烃和炔烃。
  • 2-溴苯酰胺转化为相应的3,3-二取代羟吲哚。
  • 芳基-烷基C−C 还原型交叉偶联反应。
产品可与我们的光催化剂系列一起使用: 包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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