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Merck
CN

546682

酞菁铜(II)

Dye content >99 %

别名:

CuPc, 酞菁蓝, 颜料蓝 15

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关于此项目

经验公式（希尔记法）:
C32H16CuN8
化学文摘社编号:
147-14-8
分子量:
576.07
EC Number:
205-685-1
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24878914
MDL number:
MFCD00010719
Colour Index Number:
74160
Beilstein/REAXYS Number:
4121848

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产品名称

酞菁铜(II), Dye content >99 %

InChI key

XCJYREBRNVKWGJ-UHFFFAOYSA-N

InChI

1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

SMILES string

c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12

composition

Dye content, >99%

λmax

678 nm

OLED device performance

ITO/CuPc/NPD/Alq3/C60/Mg:Ag

  • Color: green
  • Max. Luminance: 17200 Cd/m2

ITO/CuPc/NPD/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 2000 Cd/m2
  • Turn-On Voltage: 7.5 V

ITO/CuPc/NPD/CBP:FIrpic (6%)/BAlq3/LiF/Al
  • Color: blue
  • Max. EQE: 4.5 %

OPV device performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 53.1 mA/cm2
  • Open-circuit voltage (Voc): 0.57 V
  • Fill Factor (FF): 0.61
  • Power Conversion Efficiency (PCE): 4.2 %

ITO/PEDOT:PSS/CuPc/C60/BCP/Al
  • Short-circuit current density (Jsc): 18.8 mA/cm2
  • Open-circuit voltage (Voc): 0.58 V
  • Fill Factor (FF): 0.52
  • Power Conversion Efficiency (PCE): 3.6 %

Quality Level

100

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相关类别

Application


  • 一种简单的分子工程酞菁铜(II)，可作为平面钙钛矿太阳能电池的空穴传输材料，提高性能和稳定性：研究介绍了一种改性酞菁铜(II)，可提高钙钛矿太阳能电池的性能和稳定性（Yang et al., 2017）。

  • 用于高效稳定钙钛矿太阳能电池的无掺杂甲氧基取代酞菁铜(II)研究：讨论了甲氧基取代酞菁铜(II)的合成与应用，提高了钙钛矿太阳能电池的效率和稳定性（Ding et al., 2020）。

  • 基于无金属和含2-苯基苯氧基部分酞菁铜(II)的高效染料敏化太阳能电池研究：研究了用于染料敏化太阳能电池的新型酞菁，重点介绍了它们的合成和光物理特性（Ali et al., 2016）。

  • Operando HERFD-XANES和表面灵敏的Δμ分析法揭示酞菁铜(II)在CO2电还原过程中的结构演变：本研究采用先进的光谱技术研究CO2电还原过程中酞菁铜(II)的结构变化（Mei et al., 2022）。

  • 新型染料敏化光催化剂：可用于水修复的酞菁铜(II)/TiO2纳米复合材料研究：研究了使用酞菁铜(II)-TiO2复合材料作为水修复的光催化剂，展示了其在光照条件下降解污染物的有效性（Albay et al., 2016）。

存储类别

11 - Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBT0834
SHBS2892
SHBR2940
SHBP0817
SHBN0145

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A Mugarza et al.
Physical review letters, 105(11), 115702-115702 (2010-09-28)
We study the electronic mechanisms underlying the induction and propagation of chirality in achiral molecules deposited on surfaces. Combined scanning tunneling microscopy and ab initio electronic structure calculations of Cu-phthalocyanines adsorbed on Ag(100) reveal the formation of chiral molecular orbitals
Jia Liu et al.
Journal of the American Chemical Society, 133(51), 21010-21015 (2011-11-24)
The bottom-up fabrication of surface hierarchical nanostructures is of great importance for the development of molecular nanostructures for chiral molecular recognition and enantioselective catalysis. Herein, we report the construction of a series of 2D chiral hierarchical structures by trinary molecular
Medhat A Shaibat et al.
The journal of physical chemistry. B, 114(13), 4400-4406 (2010-03-17)
Cu(II)(phthalocyanine) (CuPc) is broadly utilized as an archetypal molecular semiconductor and is the most widely used blue printing pigment. CuPc crystallizes in six different forms; the chemical and physical properties are substantially modulated by its molecular packing among these polymorphs.
Masaya Hirade et al.
ACS applied materials & interfaces, 3(1), 80-83 (2011-01-05)
To enhance the performance of organic photovoltaic (OPV) cells, preparation of organic nanometer-sized pillar arrays is fascinating because a significantly large area of a donor/acceptor heterointerface having continuous conduction path to both anode and cathode electrodes can be realized. In
Yu Li Huang et al.
Langmuir : the ACS journal of surfaces and colloids, 26(5), 3329-3334 (2010-02-24)
The self-assembly of the binary molecular system comprising copper(II) phthalocyanine (CuPc) and copper-hexadecafluoro-phthalocyanine (F(16)CuPc) on graphite has been investigated by in situ low-temperature scanning tunneling microscopy (LT-STM). The adsorption of this binary molecular system on graphite results in the formation
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