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Merck
CN

CRM67618

三氯磷酸酯

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

别名:

(2,2,2-三氯-1-羟乙基)磷酸二甲酯, 美曲磷酯

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关于此项目

经验公式(希尔记法):
C4H8Cl3O4P
化学文摘社编号:
分子量:
257.44
NACRES:
NA.24
UNSPSC Code:
41116107
Beilstein/REAXYS Number:
1709434
MDL number:
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Quality Segment

product line

TraceCERT®

grade

certified reference material, TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

format

neat

storage temp.

−20°C

SMILES string

COP(=O)(OC)C(O)C(Cl)(Cl)Cl

InChI

1S/C4H8Cl3O4P/c1-10-12(9,11-2)3(8)4(5,6)7/h3,8H,1-2H3

InChI key

NFACJZMKEDPNKN-UHFFFAOYSA-N

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Trichlorfon is a broad-spectrum organophosphate insecticide used for the protection of a variety of fields and fruit crops. It is also used against fish parasites in aquaculture. It inhibits the activity of acetylcholinesterase (AChE) and causes the acetylcholine (ACh) to accumulate in the nerve synapses thereby disrupting nerve function.
Trichlorfon is not approved for use in the European Union (EU) as a plant protection agent under Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC. But a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is set for its presence in fresh/frozen fruits and tree nuts respectively as per the Reg. (EU) No 899/2012.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The trichlorfon CRM may also find the following uses:

  • Determination of trichlorfon in leek and cucumber samples by direct competitive biomimetic immunosorbent assay based on the use of a molecularly imprinted polymer
  • Development of a biomimetic immunoassay-capillary electrophoresis (BI-CE) method using quantum dot (QD) labels to determine trichlorfon in carrot, zucchini, edible rape, and leek samples
  • Analysis of phthalates and 18 insecticide residues in 46 different samples of shrimps using liquid/gas chromatography-tandem mass spectrometry (LC/GC-MS/MS) for the risk assessment of compounds on human health
  • Multi-residue determination of 238 pesticides and 78 veterinary drugs in 80 bovine milk samples by ultra-fast liquid chromatography-tandem mass spectrometry (UFLC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Evaluation of nanoflow liquid chromatography-mass spectrometry (LC-MS) to simultaneously determine 60 pesticide residues from different chemical classes in tomato, baby food, olive oil, orange, and fruit jam samples
  • Validation of a liquid chromatography-tandem mass spectrometry (LC-MS/MS) method for detection and quantification of clanobutin, dichlorvos, and naftazone in pork, beef, chicken, milk, and egg samples

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Resp. Sens. 1 - Skin Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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分析证书(COA)

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