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Merck
CN

32249

甲苯

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.7% (GC)

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关于此项目

线性分子式:
C6H5CH3
化学文摘社编号:
108-88-3
分子量:
92.14
NACRES:
NA.21
PubChem Substance ID:
329754114
eCl@ss:
39011102
UNSPSC Code:
12352005
EC Number:
203-625-9
MDL number:
MFCD00008512
Beilstein/REAXYS Number:
635760
Assay:
≥99.7% (GC)
Technique(s):
microbiological culture: suitable
Bp:
110-111 °C (lit.)
Vapor pressure:
22 mmHg ( 20 °C)
26 mmHg ( 25 °C)

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产品名称

甲苯, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.7% (GC)

InChI key

YXFVVABEGXRONW-UHFFFAOYSA-N

InChI

1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3

SMILES string

Cc1ccccc1

grade

ACS reagent
puriss. p.a.

agency

USP/NF
reag. ISO
reag. Ph. Eur.

vapor density

3.2 (vs air)

vapor pressure

22 mmHg ( 20 °C)
26 mmHg ( 25 °C)

assay

≥99.7% (GC)

form

liquid

autoignition temp.

997 °F

expl. lim.

7 %

technique(s)

microbiological culture: suitable

impurities

≤0.0001% thiophene
≤0.001% free acid (as HCl)
≤0.001% free alkali (as NaOH)
≤0.001% non-volatile matter
≤0.003% S-compounds (as S)
≤0.02% water (Karl Fischer)

color

APHA: ≤10

refractive index

n/D 1.496 (lit.)
n20/D 1.496-1.498

bp

110-111 °C (lit.)

mp

-93 °C (lit.)

density

0.865 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 ppm
Ba: ≤0.1 ppm
Bi: ≤0.1 ppm
Ca: ≤0.5 ppm
Cd: ≤0.05 ppm
Co: ≤0.02 ppm
Cr: ≤0.02 ppm
Cu: ≤0.02 ppm
Fe: ≤0.1 ppm
K: ≤0.5 ppm
Li: ≤0.1 ppm
Mg: ≤0.1 ppm
Mn: ≤0.02 ppm
Mo: ≤0.1 ppm
Na: ≤0.5 ppm
Ni: ≤0.02 ppm
Pb: ≤0.1 ppm
Sr: ≤0.1 ppm
Zn: ≤0.1 ppm

Quality Level

200

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相关类别

Application

Toulene may be used as a solvent for the preparation of 4-arm polylactide-based (PLA) star oligomer. It was used for the activation of glass slides, for in vitro test system for allergy diagnosis.

General description

Toluene, a benzene analog, is widely employed as an organic solvent. Its anaerobic biodegradation to CO2, by the denitrifying bacterium Thauera arornatica has been reported. It forms syndiotactic polystyrene-toluene molecular compound. Crystal structure of this molecular compound has been investigated by X-ray diffraction studies.

Other Notes

Pertains only in Germany: unversteuert
The article number 32249-4X2.5L will be discontinued. Please order the single bottle 32249-2.5L which is physically identical with the same exact specifications.
The article number 32249-4X2.5L-M will be discontinued. Please order the single bottle 32249-2.5L-M which is physically identical with the same exact specifications.
The article number 32249-6X1L will be discontinued. Please order the single bottle 32249-1L which is physically identical with the same exact specifications.
The article number 32249-6X1L-M will be discontinued. Please order the single bottle 32249-1L-M which is physically identical with the same exact specifications.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.9 °F - closed cup

flash_point_c

4.4 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6268
SDBB4710
SDBB4238
BCBN7364V
BCBN7363V

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Barbara I Fall et al.
Analytical chemistry, 75(3), 556-562 (2003-02-15)
The described in vitro test system for allergy diagnosis is based on microscope glass slides activated with (3-glycidyloxypropyl)trimethoxysilane. Allergen solutions are immobilized as small droplets (approximately 10 nL) on the activated glass slides with a piezoelectric arrayer. In contrast to
Structural study on syndiotactic polystyrene: 2. Crystal structure of molecular compound with toluene.
Chatani Y, et al.
Polymer, 34(8), 1620-1620 (1993)
T Biegert et al.
European journal of biochemistry, 238(3), 661-668 (1996-06-15)
Toluene is degraded anoxically to CO2 by the denitrifying bacterium Thauera aromatica. Toluene first becomes oxidized to benzoyl-CoA by O2-independent reactions. Benzoyl-CoA is then reduced to non-aromatic products by benzoyl-CoA reductase. We set out to study the reactions employed for
V Melissinaki et al.
Biofabrication, 3(4), 045005-045005 (2011-09-21)
This study reports on the production of high-resolution 3D structures of polylactide-based materials via multi-photon polymerization and explores their use as neural tissue engineering scaffolds. To achieve this, a liquid polylactide resin was synthesized in house and rendered photocurable via
Marina Shalaeva et al.
Journal of medicinal chemistry, 56(12), 4870-4879 (2013-05-29)
This study demonstrates that ΔlogP(oct-tol) (difference between logP(octanol) and logP(toluene)) describes compounds propensity to form intramolecular hydrogen bonds (IMHB) and may be considered a privileged molecular descriptor for use in drug discovery and for prediction of IMHB in drug candidates.
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