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Merck
CN

306568

氢氧化钾

semiconductor grade, pellets, 99.99% trace metals basis (Purity excludes sodium content.)

别名:

苛性钾

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关于此项目

线性分子式:
KOH
化学文摘社编号:
分子量:
56.11
PubChem Substance ID:
eCl@ss:
38100303
UNSPSC Code:
12352106
NACRES:
NA.21
EC Number:
215-181-3
MDL number:
Assay:
99.99% trace metals basis (Purity excludes sodium content.)
Grade:
semiconductor grade
Form:
pellets
Solubility:
water: soluble
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产品名称

氢氧化钾, semiconductor grade, pellets, 99.99% trace metals basis (Purity excludes sodium content.)

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

InChI

1S/K.H2O/h;1H2/q+1;/p-1

SMILES string

[OH-].[K+]

grade

semiconductor grade

vapor pressure

1 mmHg ( 719 °C)

assay

99.99% trace metals basis (Purity excludes sodium content.)

form

pellets

composition

KOH, >85.0%

impurities

15% water

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

Quality Level

solubility

water: soluble

cation traces

Na: ≤500.0 ppm

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Application

与碲粉结合,介导芳香族羰基化合物的吡那酮化反应。
氢氧化钾可用于:
  • 作为碱,从胺和乙醇合成亚胺。
  • 作为仲醇与伯醇β-烷基化反应的碱,无需任何过渡金属催化剂。
  • 结合铝用于芳香醛的吡啶化和受阻酮的还原。
  • 作为沉淀剂,采用改性水热法制备 MnZn 铁氧体纳米粒子(Mn0.8Zn0.2Fe2O4铁氧体纳米粒子)。

General description

氢氧化钾(KOH)又称苛性钾。它被用作许多含钾产品的重要前体。

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
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历史批次信息供参考:

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Qilun Wang et al.
Nature communications, 11(1), 4246-4246 (2020-08-28)
Water electrolysis offers a promising energy conversion and storage technology for mitigating the global energy and environmental crisis, but there still lack highly efficient and pH-universal electrocatalysts to boost the sluggish kinetics for both cathodic hydrogen evolution reaction (HER) and
Ian T McCrum et al.
The journal of physical chemistry. C, Nanomaterials and interfaces, 122(29), 16756-16764 (2018-09-28)
The effect of the alkali-metal cation (Li+, Na+, K+, and Cs+) on the non-Nernstian pH shift of the Pt(554) and Pt(533) step-associated voltammetric peak is elucidated over a wide pH window (1-13), through computation and experiment. In conjunction with our
Haochen Zhang et al.
Nature communications, 10(1), 3340-3340 (2019-07-28)
Electroreduction of carbon dioxide to hydrocarbons and oxygenates on copper involves reduction to a carbon monoxide adsorbate followed by further transformation to hydrocarbons and oxygenates. Simultaneous improvement of these processes over a single reactive site is challenging due to the
Maria D Cabezas et al.
Methods in cell biology, 119, 261-276 (2014-01-21)
The extracellular matrix (ECM) is a complex, spatially inhomogeneous environment that is host to myriad cell-receptor interactions that promote changes in cell behavior. These biological systems can be probed and simulated with engineered surfaces, but doing so demands careful control
Takahiro Naito et al.
ChemSusChem, 13(22), 5921-5933 (2020-09-03)
Hydrogen production from renewable energy and ubiquitous water has a potential to achieve sustainability, although current water electrolyzers cannot compete economically with the fossil fuel-based technology. Here, we evaluate water electrolysis at pH 7 that is milder than acidic and alkaline

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