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Merck
CN

30417

Sigma-Aldrich

磷酸

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥85%

别名:

正磷酸

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About This Item

线性分子式:
H3PO4
CAS号:
分子量:
98.00
Beilstein:
1921286
EC 号:
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:

等级

ACS reagent
puriss. p.a.

质量水平

Agency

USP/NF
reag. ISO
reag. Ph. Eur.

蒸汽密度

3.4 (vs air)

蒸汽压

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

方案

≥85%

表单

liquid

杂质

reducing impurities, in accordance
residual solvents, in accordance
substances precipitated by ammonia, in accordance
≤0.001% KMnO4 red. matter (as O)
≤0.001% heavy metals (as Pb)
≤0.001% in water insoluble matters
≤0.001% volatile acids (as CH3COOH)

沸点

158 °C (lit.)

mp

~40 °C (lit.)

密度

1.685 g/mL at 25 °C (lit.)

痕量阴离子

chloride (Cl-): ≤2 mg/kg
fluoride (F-): ≤1 mg/kg
nitrate (NO3-): ≤3 mg/kg
phosphite, hypophosphite (as H3PO3): ≤20 mg/kg
phosphite, hypophosphite (as H3PO3): in accordance
sulfate (SO42-): ≤30 mg/kg

痕量阳离子

As: ≤0.5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤5 mg/kg
K: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤0.5 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sb: ≤2 mg/kg
Zn: ≤2 mg/kg

SMILES字符串

OP(O)(O)=O

适用性

passes test for appearance of solution

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

基因信息

human ... SRC(6714)

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应用


  • Rh/非手性磷酸协同催化羰基叶立德与醌单亚胺的[3+3]环化:苯并二氧杂双环[3.2.1]辛烷支架的合成。:研究证明了磷酸在[3+3]环化反应中的催化作用,实现了复杂有机支架的高效合成(Tu et al., 2024)。

其他说明

浓磷酸大约为 85% H3PO4(水溶液)。
货号 30417-4X2.5L 的产品即将停产。请订购单瓶装 30417-2.5L 产品,其物理特性及规格上与停产商品完全一样。
货号为30417-4X2.5L-M 的产品即将停产。请订购单瓶装30417-2.5L-M产品,其物理特性及规格上与停产商品完全一样。
货号 30417-6X1L 的产品即将停产。请订购单瓶装 30417-1L 产品,其物理特性及规格上与停产商品完全一样。
货号30417-6X1L-M的产品即将停产。请订购30417-1L-M单瓶装,因为其物理参数与上述产品本质相同。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)
J M Fujitaki et al.
Biochemistry, 20(12), 3658-3664 (1981-06-09)
Phosphorus-31 nuclear magnetic resonance (31P NMR) is used to investigate acid-labile phosphorylation of histone H4. 31P NMR detects phosphorylated histidine residues in in vitro enzymatically phosphorylated H4. The source of kinase is nuclei from either regenerating rat liver or Walker-256
D S Marinier et al.
Journal of lipid research, 29(9), 1237-1243 (1988-09-01)
In order to study the lipid composition of human white matter, we have developed a 31P NMR spectroscopy method, which allows the determination and quantitation of the main phospholipids found in biological membranes. The technique is based upon the use
P Meneses et al.
Journal of lipid research, 29(5), 679-689 (1988-05-01)
The common phospholipids from biological sources were quantitated using phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy in conjunction with an analytical reagent composed of two parts: 1) 2 ml of reagent chloroform in which was dissolved 0.01-100 mg of crude tissue
Li Yan Chan et al.
The Journal of organic chemistry, 78(17), 8826-8832 (2013-08-07)
A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.

实验方案

Folic acid vs. folate differences and biological activities; implications in fortified foods and supplements for human health.

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