等级
ACS reagent
质量水平
Agency
suitable for EPA 300
检测方案
≥97.0%
形式
powder or crystals
自燃温度
914 °F
杂质
≤0.01% insolubles
mp
271 °C (lit.)
痕量阴离子
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.01%
痕量阳离子
Ca: ≤0.01%
Fe: ≤0.001%
K: ≤0.005%
heavy metals (as Pb): ≤0.001%
SMILES字符串
[Na+].[O-]N=O
InChI
1S/HNO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1
InChI key
LPXPTNMVRIOKMN-UHFFFAOYSA-M
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一般描述
亚硝酸钠(NaNO2)是一种无机化合物,通常用作化学有机合成中的试剂和催化剂。
应用
亚硝酸钠可用作试剂用于以下反应:
它还可以在有机合成中用作硝化剂。比如,NaNO2 用于直接C-H硝化、异硝化和通过过渡金属催化的交叉偶联反应的硝化。
- 将胺转换重氮衍生物的桑德迈反应和硝化反应。
- 在氧气作为最终氧化剂的参与下形成氧化C-C键的反应。
- 在K2S2O8参与下的烯烃氧化碳化反应。
它还可以在有机合成中用作硝化剂。比如,NaNO2 用于直接C-H硝化、异硝化和通过过渡金属催化的交叉偶联反应的硝化。
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Ox. Sol. 3
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Mikrochimica acta, 186(9), 595-595 (2019-08-04)
A cyclic voltammetric method is described for the determination of nitrite by using a multiwalled carbon nanotube paste electrode (MWCNT) that was modified with chitosan-functionalized silver nanoparticles (Chit-AgNPs). The AgNPs were prepared by one step procedure using chitosan as stabilizing
International journal of food microbiology, 14(1), 77-91 (1991-10-01)
An automated turbidimetric system using multiwelled plates was used to examine the effects of different combinations of NaCl (0.5-8.0% w/v), NaNO2 (0-400 micrograms/ml) pH (4.6-7.4) and temperature (5-30 degrees C) on the growth of Listeria monocytogenes in tryptone soya broth.
Scandinavian journal of immunology, 61(1), 1-9 (2005-01-13)
Abstract High-mobility group box chromosomal protein 1 (HMGB1) is a protein with both intranuclear functions and extracellular cytokine-like effects. In this report, we study possible candidate receptors for HMGB1 on macrophages (Mphi) and define pathways activated by HMGB1 binding. Bone
Concise Encyclopedia Chemistry, 999-999 (1994)
Concise Encyclopedia Chemistry, 556-556 (1994)
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