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Merck
CN

179973

Sigma-Aldrich

丙酮

Laboratory Reagent, ≥99.5%

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线性分子式:
CH3COCH3
CAS号:
分子量:
58.08
Beilstein:
635680
EC 号:
MDL编号:
UNSPSC代码:
12352115
eCl@ss:
39021201
PubChem化学物质编号:
NACRES:
NA.21

等级

Laboratory Reagent

质量水平

蒸汽密度

2 (vs air)

蒸汽压

184 mmHg ( 20 °C)

检测方案

≥99.5%

形式

liquid

expl. lim.

13.2 %

杂质

≤0.5% water

蒸发残留物

≤0.002%

折射率

n20/D 1.359 (lit.)

pH值(酸碱度)

5-6 (20 °C, 395 g/L)

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

密度

0.791 g/mL at 25 °C (lit.)

格式

neat

SMILES字符串

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

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一般描述

丙酮是极性有机溶剂。 在混合 TiO 2 -稀土氧化物存在下可发生光催化氧化。

应用

丙酮在 Mg-Al 层状双氢氧化物 (LDH) 作为催化剂,Cl - 和/或 CO 3 2- 作为补偿阴离子的存在下发生醛化反应,得到二丙酮醇和异亚丙基丙酮作为主要产物。在二肽催化剂存在下,其与各种靛红的对映选择性羟醛缩合形成 1-烷基 3-(2-氧丙基)-3-羟基吲哚-2-酮。丙酮水溶液可用作高锰酸钾氧化炔烃为 1,2-二酮的介质。
丙酮的发光强度取决于溶液组分。丙酮吸收UV光,导致丙酮光分解和放射性产物。

象形图

FlameExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

靶器官

Central nervous system

补充剂危害

WGK

WGK 1

闪点(°F)

1.4 °F

闪点(°C)

-17.0 °C

法规信息

监管及禁止进口产品

分析证书(COA)

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. Who do I contact about larger solvent volume needs?

    Email us at labessentials@sial.com or visit Sigma-Aldrich Fine Chemicals for development and manufacturing-scale inquiries: safcglobal@sial.com

  4. How do I know what packaging options are available for a solvent?

    The Solvent Center gives you the ability to review all the specifications associated with our solvent packaging. This includes physical dimensions, closure types, dispensing methods, UN/DOT Rating as well as solvent compatibility. Visit the Solvent Center.

  5. Who do I contact if I need a solvent blend, which you do not carry?

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  6. The dispensing of solvents provides some challenges due to the number of container options available. What dispensing options are available for each container?

    The Sigma-Aldrich Solvent Center provides numerous dispensing options for each container type. For a complete listing of all our dispensing options, Visit the Solvent Center.

  7. Which solvent grade should I be using for my application?

    Sigma-Aldrich Solvent Applications Table gives a guideline to common applications and the appropriate solvent grades.  Visit: Solvents

  8. What are the options for drying solvents? 

    Sigma-Aldrich offers a full range of high-purity solvents with extremely low water levels specifically manufactured for moisture sensitive Organic and Biotech applications.  Sigma-Aldrich also carries various drying agents such as molecular sieves, which are typically compatible with organic solvents.

  9. What apparatus do you recommend for HPLC solvent filtration?

    The Sigma-Aldrich Vacuum Filtration Assembly gives you all the components you need including: funnel top, fritted glass funnel support, filtration flask, aluminum clamp, and silicone stopper.  The Acrodisc Syringe Filters offer high quality filtration for analytical samples, certified for HPLC to ensure low extractable and available in a broad range of membranes to meet sample compatibility requirements.

  10. Can you recommend a Solvent Extractor for organics from aqueous solution?

    Solvent extractors are often used for the quantitative extraction of organics from aqueous solutions and separations in immunoassays. The MIXXOR system has been applied successfully in many laboratory solvent extraction operations and is ideal for the rapid screening of alternative solvents for specific extraction problems.

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  12. What is the Department of Transportation shipping information for this product?

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  13. My question is not addressed here, how can I contact Technical Service for assistance?

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Preparation of 1,2-diketones: oxidation of alkynes by potassium permanganate in aqueous acetone
Srinivasan NS and Donald GL
The Journal of Organic Chemistry, 44(9), 1574-1574 (1979)
Aldol condensation of acetone over layered double hydroxides of the meixnerite type.
Tichit D, et al.
Applied Clay Science, 13(5), 401-415 (1998)
An investigation on photocatalytic activities of mixed TiO2-rare earth oxides for the oxidation of acetone in air.
Lin J and Jimmy CY.
Journal of Photochemistry and Photobiology A: Chemistry, 116(1), 63-67 (1998)
Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a
Oleksiy Krupin et al.
Optics express, 21(1), 698-709 (2013-02-08)
Straight long-range surface plasmon waveguides are demonstrated as biosensors for the detection of cells, proteins and changes in the bulk refractive index of solutions. The sensors consist of 5 μm wide 22 nm thick Au stripes embedded in polymer (CYTOP™)

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