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Merck
CN

792527

Sigma-Aldrich

咪唑

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%

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别名:
1,3-二氮杂-2,4-环戊二烯, 甘恶啉
经验公式(希尔记法):
C3H4N2
CAS号:
分子量:
68.08
Beilstein:
103853
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

等级

ACS reagent
anhydrous

质量水平

蒸汽压

<1 mmHg ( 20 °C)

产品线

Redi-Dri

检测方案

≥99%

形式

solid

质量

free-flowing

杂质

≤0.2% water

灼烧残渣

≤0.1%

pH值(酸碱度)

9.5-11.0 (25 °C, 5% in H2O)

pKa (25 °C)

6.95

bp

256 °C (lit.)

mp

88-91 °C (lit.)

痕量阳离子

Fe: ≤0.001%

SMILES字符串

c1c[nH]cn1

InChI

1S/C3H4N2/c1-2-5-3-4-1/h1-3H,(H,4,5)

InChI key

RAXXELZNTBOGNW-UHFFFAOYSA-N

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应用

咪唑由于具有两性性质和快速的质子转移能力,可作为质子转移试剂用于多孔有机聚合物合成。
咪唑作为催化剂的用途:
  • 在氯硅烷/DMF存在下,醇、羧酸和胺类物质的硅烷化反应。      
  • 羧酸和光气制备相应酰氯。      
  • 咪唑-PPh3/I2催化体系用于醇变为碘化物的转换反应。      
  • 咪唑-PPh3/I2用于二醇脱氧反应。      

特别适用于 pH 6.2-7.8 范围内的缓冲液

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C

WGK

WGK 2

闪点(°F)

293.0 °F

闪点(°C)

145 °C


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商品

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

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