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Merck
CN

33149

二苯胺

puriss. p.a., suitable for redox indicator, ACS reagent, reag. Ph. Eur., ≥98% (GC)

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关于此项目

线性分子式:
(C6H5)2NH
化学文摘社编号:
122-39-4
分子量:
169.22
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
329754463
EC Number:
204-539-4
Beilstein/REAXYS Number:
508755
MDL number:
MFCD00003014

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产品名称

二苯胺, puriss. p.a., suitable for redox indicator, ACS reagent, reag. Ph. Eur., ≥98% (GC)

InChI key

DMBHHRLKUKUOEG-UHFFFAOYSA-N

InChI

1S/C12H11N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

SMILES string

N(c1ccccc1)c2ccccc2

grade

ACS reagent
puriss. p.a.

agency

reag. Ph. Eur.

vapor density

5.82 (vs air)

vapor pressure

1 mmHg ( 108 °C)

assay

≥98% (GC)

autoignition temp.

1175 °F

technique(s)

titration: suitable

impurities

≤0.01% insoluble in ethanol

ign. residue

≤0.03% (as SO4)

bp

302 °C (lit.)

mp

50-53 °C (lit.)
52.5-54.0 °C

anion traces

nitrate (NO3-): in accordance

cation traces

Fe: ≤10 mg/kg

suitability

suitable for redox indicator

Quality Level

200

Gene Information

human ... UGT1A4(54657)

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Packaging

在惰性气体下装瓶

Application

Diphenylamine may be used in the preparation of diphenylamine reagent, which is employed for the quantitative estimation of DNA from various biological sources by colorimetric method. It may be used in the preparation of poly(diphenylamine), via electrochemical and chemical polymerization methods.

General description

Diphenylamine is an N-substituted derivative of aniline.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

target_organs

Kidney,Liver,spleen

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN9957
BCCM2631
BCCK2570
BCCH5691
BCCF4175

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An improved diphenylamine method for the estimation of deoxyribonucleic acid.
Giles KW and Myers A.
Nature, 206(4979), 93-93 (1965)
A study of the conditions and mechanism of the diphenylamine reaction for the colorimetric estimation of deoxyribonucleic acid.
K BURTON
The Biochemical journal, 62(2), 315-323 (1956-02-01)
Soluble and methane sulfonic acid doped poly (diphenylamine)-synthesis and characterization.
Wen T-C, et al.
Materials Letters, 57(2), 280-290 (2002)
Margot Van der Jeught et al.
Stem cells and development, 22(2), 296-306 (2012-07-13)
In embryonic stem cell culture, small molecules can be used to alter key signaling pathways to promote self-renewal and inhibit differentiation. In mice, small-molecule inhibition of both the FGF/MEK/Erk and the GSK3β pathways during preimplantation development suppresses hypoblast formation, and
Sarah G Pati et al.
Environmental science & technology, 46(21), 11844-11853 (2012-09-29)
Dioxygenation of aromatic rings is frequently the initial step of biodegradation of organic subsurface pollutants. This process can be tracked by compound-specific isotope analysis to assess the extent of contaminant transformation, but the corresponding isotope effects, especially for dioxygenation of
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