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Merck
CN

05581

Supelco

乙酰丙酮

analytical standard

别名:

2,4-戊二酮

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About This Item

线性分子式:
CH3COCH2COCH3
CAS号:
分子量:
100.12
Beilstein:
741937
EC 号:
MDL编号:
UNSPSC代码:
41116107
eCl@ss:
39021208
PubChem化学物质编号:
NACRES:
NA.24

等级

analytical standard

质量水平

蒸汽密度

3.5 (vs air)

蒸汽压

6 mmHg ( 20 °C)

方案

≥99.6% (GC)

自燃温度

662 °F

保质期

limited shelf life, expiry date on the label

expl. lim.

11.4 %

技术

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.452 (lit.)
n20/D 1.452

沸点

140.4 °C (lit.)

mp

−23 °C (lit.)

溶解性

H2O: soluble

密度

0.975 g/mL at 25 °C (lit.)

应用

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

包装形式

neat

SMILES字符串

CC(=O)CC(C)=O

InChI

1S/C5H8O2/c1-4(6)3-5(2)7/h3H2,1-2H3

InChI key

YRKCREAYFQTBPV-UHFFFAOYSA-N

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一般描述

乙酰丙酮是 β-二酮,含两个羰基和一个活性亚甲基。

应用

乙酰丙酮用作挥发性洗脱液改性剂,在用超高压-液相色谱-电喷雾串联质谱法(UHPLC-ESI-MS)定量能量代谢物时,可补救金属阳离子造成的不利影响。也用作醛的衍生剂。(3

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

95.0 °F - closed cup

闪点(°C)

35 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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访问文档库

Controlling detrimental effects of metal cations in the quantification of energy metabolites via ultrahigh pressure-liquid chromatography-electrospray-tandem mass spectrometry by employing acetylacetone as a volatile eluent modifier
Siegel D, et al.
Journal of Chromatography A, 1294(2), 87-97 (2013)
Automatized flow-batch method for fluorescent determination of free glycerol in biodiesel samples using on-line extraction
Lima MB, et al.
Talanta, 89(2), 21-26 (2012)
2, 4-pentanedione
Ballantyne B
Journal of Applied Toxicology, 21(2), 165-171 (2001)
Liquid-phase microextraction with in-drop derivatization combined with microvolume fluorospectrometry for free and hydrolyzed formaldehyde determination in textile samples
Saenz M, et al.
Analytica Chimica Acta, 687(1), 50-55 (2011)
Rolando R Lozada-García et al.
Physical chemistry chemical physics : PCCP, 14(10), 3450-3459 (2012-02-07)
The photochemistry of the chelated enol form of acetylacetone (AcAc) was investigated by UV excitation of the S(2) state at 266 nm in parahydrogen matrices, complemented by experiments in neon and normal hydrogen matrices. Infrared (IR) spectroscopy, combined with theoretical

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