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Merck
CN

M22601

Sigma-Aldrich

1-(2-甲氧苯基)哌嗪

98%

别名:

1-(2-甲氧基苯基)哌嗪, 1-(o-甲氧基苯基)哌嗪, 1-(邻甲氧苯基)哌嗪, N-(2-甲氧基苯基)哌嗪, N-(邻甲氧基苯基)哌嗪, 邻甲氧基苯基哌嗪

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About This Item

经验公式(希尔记法):
C11H16N2O
CAS号:
分子量:
192.26
Beilstein:
167888
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

折射率

n20/D 1.575 (lit.)

沸点

130-133 °C/0.1 mmHg (lit.)

mp

35-40 °C (lit.)

密度

1.095 g/mL at 25 °C (lit.)

SMILES字符串

COc1ccccc1N2CCNCC2

InChI

1S/C11H16N2O/c1-14-11-5-3-2-4-10(11)13-8-6-12-7-9-13/h2-5,12H,6-9H2,1H3

InChI key

VNZLQLYBRIOLFZ-UHFFFAOYSA-N

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应用

1-(2-甲氧苯基)哌嗪可用于:
  • 通过Aza-Michael加成反应官能化吡唑乙烯酮 (pyrazolylvinyl ketone) 类化合物。
  • 制备环胺取代Tröger碱衍生物。
  • 与[(1-甲基-2-巯基咪唑-5-基)羰基]琥珀酰亚胺反应,制备官能化双(巯基咪唑)硼酸酯。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Rhenium (I) tricarbonyl complexes with mercaptoimidazolylborate ligands bearing piperazine fragments
Garcia R, et al.
J. Chem. Soc., Dalton Trans., 6(22), 4236-4241 (2002)
P Molander et al.
Journal of chromatography. A, 892(1-2), 67-74 (2000-10-25)
A temperature-programmed packed capillary LC method with large-volume injection on-column focusing has been developed for screening and determination of 1-(2-methoxyphenyl)piperazine derivatives of airborne toluene-2,4-diisocyanate, toluene-2,6-diisocyanate, hexamethylenediisocyanate and methylenebisphenyl-4,4-diisocyanate, based on sampling methods described in MDHS 25/3. Injection volumes up to
Hartmut Henneken et al.
Journal of environmental monitoring : JEM, 8(10), 1014-1019 (2007-01-24)
Diffusive sampling of methyl isocyanate (MIC) on 4-nitro-7-piperazinobenzo-2-oxa-1,3-diazole (NBDPZ)-coated glass fibre (GF) filters is strongly affected by high relative humidity (RH) conditions. It is shown that the humidity interference is a physical phenomenon, based on displacement of reagent from the
L Pawłowski
Polish journal of pharmacology and pharmacy, 35(4), 319-326 (1983-01-01)
1-(o-methoxyphenyl)-piperazine (o-MPP) is regarded as an antagonist of the dopamine receptor. Its effects were studied for the hind limb flexor reflex in the spinal rat, the body temperature in rats maintained at ambient temperature of 28 degrees C and stereotypy
Christian Mattsson et al.
International journal of hygiene and environmental health, 211(3-4), 458-462 (2007-09-18)
Occupational exposure to toluene diisocyanate (TDI) is a known occupational hazard and the occupational exposure limits in air are very low. One of the most common methods to monitor exposure to isocyanates is to sample air through filters impregnated with

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