D38308
2,4′-二溴苯乙酮
>98%
别名:
4′-溴苯甲酰甲基溴
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关于此项目
线性分子式:
BrC6H4COCH2Br
化学文摘社编号:
分子量:
277.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-783-6
Beilstein/REAXYS Number:
607604
MDL number:
Assay:
>98%
Form:
crystals
产品名称
2,4′-二溴苯乙酮, >98%
InChI key
FKJSFKCZZIXQIP-UHFFFAOYSA-N
InChI
1S/C8H6Br2O/c9-5-8(11)6-1-3-7(10)4-2-6/h1-4H,5H2
SMILES string
BrCC(=O)c1ccc(Br)cc1
assay
>98%
form
crystals
mp
108-110 °C (lit.)
Quality Level
Gene Information
human ... PLA2G2A(5320)
rat ... Pla2g2a(29692)
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Application
在 SnCl2 或 SmI3 存在的情况下与醛发生缩合反应以生成 α,β-不饱和酮。还用于羧酸的酯化反应。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Synthetic Communications, 23, 271-271 (1993)
Tetrahedron Letters, 34, 4547-4547 (1993)
Tetrahedron, 49, 9735-9735 (1993)
Angelo J Magro et al.
Acta crystallographica. Section D, Biological crystallography, 61(Pt 12), 1670-1677 (2005-11-23)
The crystal structure of an acidic phospholipase A(2) isolated from Bothrops jararacussu venom (BthA-I) chemically modified with p-bromophenacyl bromide (BPB) has been determined at 1.85 Angstroms resolution. The catalytic, platelet-aggregation inhibition, anticoagulant and hypotensive activities of BthA-I are abolished by
Wen-Hsin Liu et al.
Toxicology letters, 185(2), 102-109 (2009-01-03)
In view of the controversial role of catalytic activity on the cytotoxicity of phospholipase A(2) (PLA(2)), the present study is conducted to explore whether PLA(2) induces apoptotic process of human leukemia U937 cells through catalytic activity-independent pathway. Modification of His-48
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