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Merck
CN

933953

Sigma-Aldrich

Sodium difluoro(oxalato)borate

greener alternative

≥99%, battery grade

别名:

NaDFOB, NaFOB, Sodium difluoro(ethanedioato)borate

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About This Item

经验公式(希尔记法):
C2BF2NaO4
分子量:
159.82
MDL编号:
UNSPSC代码:
12352104
NACRES:
NA.21

等级

battery grade

质量水平

描述

Application: Battery manufacturing

方案

≥99%

表单

powder

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

≤0.2% H2O

痕量阴离子

chloride (Cl-): ≤50 ppm
sulfate (SO42-): ≤20 ppm

痕量阳离子

Ca: ≤20 ppm
K: ≤20 ppm
Mg: ≤20 ppm

应用

battery manufacturing

环保替代产品分类

SMILES字符串

O=C1C(O[B-](F)(F)([Na+])O1)=O

一般描述

Sodium difluoro(oxalato)borate, also referred to as NaDFOB, is a high-purity and low-water content white crystalline powder that has become increasingly popular in the field of battery technology. NaDFOB is the sodium equivalent of lithium difluoro(oxalato)borate and is soluble in polar organic solvents (>1.0 M in carbonates), making it ideal for use in battery electrolytes. It exhibits excellent electrochemical stability, surpassing NaClO4, with NaDFOB-based carbonate electrolytes showing electrochemical stability windows above 5.5V vs Na+/Na. Our NaDFOB is manufactured to the highest standards to ensure its purity, enabling it to be used effectively in a wide range of battery applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

应用

Sodium-difluoro(oxalato)borate, anhydrous and battery-grade with a purity of ≥99%, is a versatile electrolyte additive for sodium-ion batteries (SIBs). NaDFOB demonstrates superior compatibility with a range of solvents commonly employed in SIBs, unlike NaClO4 and NaPF6, which exhibit solvent-dependent performances. Additionally, NaDFOB is stable and does not produce any toxic or hazardous substances upon contact with air and water. A recent study found that the incorporation of NaDFOB as an additive significantly enhances the charge-discharge capacity and cycling performance of graphite anodes. Another study suggests that NaDFOB contributes to the formation of a stable solid electrolyte interphase (SEI) film on the surface of graphite anodes, resulting in a highly stable electrolyte/electrode interface. With these benefits, Sodium-difluoro(oxalato)borate is a promising solution for improving the performance and stability of sodium-ion batteries in various applications.

象形图

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警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Juner Chen et al.
Chemical communications (Cambridge, England), 51(48), 9809-9812 (2015-05-20)
A new electrolyte salt, sodium-difluoro(oxalato)borate (NaDFOB), was synthesized and studied, which enables excellent reversible capacity and high rate capability when used in Na/Na0.44MnO2 half cells. NaDFOB has excellent compatibility with various common solvents used in Na-ion batteries, in strong contrast
Application of Partially Fluorinated Ether for Improving Performance of Lithium/Sulfur Batteries
Lu Hai, et al.
Journal of the Electrochemical Society, 162 (2015)
Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode
Yang-yang Yao, et al.
International Journal of Electrochemistry, 21, 387-392 (2015)

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