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Merck
CN

932671

Sigma-Aldrich

红菲咯啉

别名:

4,7-二苯基-1,10-菲罗啉, BPhen

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About This Item

经验公式(希尔记法):
C24H16N2
CAS号:
分子量:
332.40
Beilstein:
261048
MDL编号:
UNSPSC代码:
23151817
NACRES:
NA.21

等级

sublimed grade

质量水平

描述

µe ≈ 3.0 x 10-4 cm2V-1s-1

方案

≥99% (H-NMR)

表单

powder

缺失

0.5% TGA, >240ºC (weight loss)

mp

218-220 °C (lit.)

溶解性

THF: soluble
chloroform: soluble
dichloromethane: soluble

λmax

272 nm in THF

荧光

λem 379 nm in THF

轨道能量

HOMO 6.4 eV 
LUMO 3.0 eV 

SMILES字符串

c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5

InChI

1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H

InChI key

DHDHJYNTEFLIHY-UHFFFAOYSA-N

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应用

Intermolecular charge-transfer states at the interface between electron donating (D) and accepting (A) materials are crucial for the operation of organic electronics, such as solar cells, transistors and organic light-emitting diodes (OLEDs). The 4,7-Diphenyl-1,10-phenanthroline, also known as Bathophenanthroline (Bphen) enables use as Electron Transport / Hole Blocking Layer (ETL / HBL) in your organic electronic devices. It has a μe of about 3.0 x 10-4 cm2 V−1 s−1 and is solution-processable.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Emissive and charge-generating donor-acceptor interfaces for organic optoelectronics with low voltage losses
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Nature Materials, 18, 459-464 (2019)
Light outcoupling efficiency enhancement in organic light emitting diodes using an organic scattering layer
Grover Rakhi, et al.
Physica Status Solidi RRL: Rapid Research Letters, 8, 81?85-81?85 (2014)
Initial photochemical stability in perovskite solar cells based on the Cu electrode and the appropriate charge transport layers
Tan, Wenjun, et al.
Synthetic Metals, 246, 101-107 (2018)
Highly efficient inverted organic light-emitting devices adopting solution-processed double electron-injection layers.
Chen, Y. et al.
Organic Electronics, 66, 1-6 (2019)
Strong light-matter coupling for reduced photon energy losses in organic photovoltaics
Nikolis, V. et al.
Nature Communications, 10, 1-8 (2019)

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