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Merck
CN

932671

红菲咯啉

greener alternative

别名:

4,7-二苯基-1,10-菲罗啉, BPhen

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经验公式(希尔记法):
C24H16N2
化学文摘社编号:
分子量:
332.40
Beilstein:
261048
MDL编号:
UNSPSC代码:
23151817
NACRES:
NA.21
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等级

sublimed grade

质量水平

描述

µe ≈ 3.0 x 10-4 cm2V-1s-1
Electron Transport Layer

方案

≥99% (H-NMR)

表单

powder

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

缺失

0.5% TGA, >240ºC (weight loss)

mp

218-220 °C (lit.)

溶解性

THF: soluble
chloroform: soluble
dichloromethane: soluble

λmax

272 nm in THF

荧光

λem 379 nm in THF

轨道能量

HOMO 6.4 eV 
LUMO 3.0 eV 

环保替代产品分类

SMILES字符串

c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5

InChI

1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H

InChI key

DHDHJYNTEFLIHY-UHFFFAOYSA-N

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应用

Intermolecular charge-transfer states at the interface between electron donating (D) and accepting (A) materials are crucial for the operation of organic electronics, such as solar cells, transistors and organic light-emitting diodes (OLEDs). The 4,7-Diphenyl-1,10-phenanthroline, also known as Bathophenanthroline (Bphen) enables use as Electron Transport / Hole Blocking Layer (ETL / HBL) in your organic electronic devices. It has a μe of about 3.0 x 10-4 cm2 V−1 s−1 and is solution-processable.

特点和优势

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Light outcoupling efficiency enhancement in organic light emitting diodes using an organic scattering layer
Grover Rakhi, et al.
Physica Status Solidi RRL: Rapid Research Letters, 8, 81?85-81?85 (2014)
Highly efficient inverted organic light-emitting devices adopting solution-processed double electron-injection layers.
Chen, Y. et al.
Organic Electronics, 66, 1-6 (2019)
Strong light-matter coupling for reduced photon energy losses in organic photovoltaics
Nikolis, V. et al.
Nature Communications, 10, 1-8 (2019)
Emissive and charge-generating donor-acceptor interfaces for organic optoelectronics with low voltage losses
Ullbrich, S. et al.
Nature Materials, 18, 459-464 (2019)
Initial photochemical stability in perovskite solar cells based on the Cu electrode and the appropriate charge transport layers
Tan, Wenjun, et al.
Synthetic Metals, 246, 101-107 (2018)

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