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主要文件

安全信息

900783

Sigma-Aldrich

二氧化硅

mesoporous MCM-48, <15 μm particle size, pore size 3 nm, thiol functionalized

别名:

Mesoporous silica, Thiol functionalized MCM-48, Thiol functionalized mesoporous slica

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About This Item

UNSPSC代码:
12352309
NACRES:
NA.23

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质量水平

表单

solid

表面积

1400-1600 m2/g

粒径

<15 μm

孔径

0.4-0.6 cm3/g pore volume
2-4 nm pore diameter
3 nm pore size

官能团

thiol

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此商品
PNS1010P6782P8250
biological source

bovine

biological source

-

biological source

-

biological source

horseradish

technique(s)

flow cytometry: suitable

technique(s)

-

technique(s)

-

technique(s)

-

form

solution

form

liquid

form

essentially salt-free, lyophilized powder

form

essentially salt-free, lyophilized powder

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

300

应用

The unique physical properties such as high surface areas and ordered pore structure of mesoporous silica combined with the selectivity of amine and thiol functional groups make them useful for diverse applications. For example amine and thiol modified mesoporous silica finds applications in CO2 sequestration, heavy metal (such as Pb, Fe, Au etc.) removal from waste water or industrial waste streams.[1][2] Also, the ability of the amine and thiol modified mesoporous silica to bind the metallic nanoparticles such as Pt or Pd render them useful as novel catalytic support.[3] The functionalization of mesoporous silica with amine and thiol also makes them useful for entrapping biological entities and for investigations involving the study of the effect of quantum confinements of molecules/solvent within the ordered mesopores.[4][5]

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Warning

危险声明

危险分类

Aquatic Chronic 3 - Skin Sens. 1

储存分类代码

13 - Non Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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    Bob Grünberg et al.
    Chemistry (Weinheim an der Bergstrasse, Germany), 10(22), 5689-5696 (2004-10-08)
    The adsorption of water in two mesoporous silica materials with cylindrical pores of uniform diameter, MCM-41 and SBA-15, was studied by 1H MAS (MAS=magic angle spinning) and static solid-state NMR spectroscopy. All observed hydrogen atoms are either surface -SiOH groups
    Aoife M Burke et al.
    Journal of hazardous materials, 164(1), 229-234 (2008-09-23)
    Here we demonstrate aminopropyl and mercatopropyl functionalised and bi-functionalised large pore mesoporous silica spheres to extract various metal ions from aqueous solutions towards providing active sorbents for mitigation of metal ion pollution. Elemental analysis (EA) and FTIR techniques were used
    Amrit Kumar et al.
    Angewandte Chemie (International ed. in English), 54(48), 14372-14377 (2015-10-07)
    Sequestration of CO2, either from gas mixtures or directly from air (direct air capture, DAC), could mitigate carbon emissions. Here five materials are investigated for their ability to adsorb CO2 directly from air and other gas mixtures. The sorbents studied
    Synthesis of Gold Catalysts Supported on Mesoporous Silica Materials: Recent Developments.
    Gutierrez LF, et al.
    Catalysts, 1, 97-154 (2011)
    T Suami et al.
    Carbohydrate research, 53(2), 239-246 (1977-02-01)
    The aminocyclitol antibiotic neamine has been modified chemically by removing one or two hydroxyl groups from the 2-deoxystreptamine moiety to give 5- and 6- deoxyneamines (5 and 10), as well as 5,6-dideoxyneamine (15). Their antimicrobial activities were determined against several

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