所有图片(1)
About This Item
经验公式（希尔记法）:
C2H3FO2S
CAS号:
分子量:
110.11
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
95%
表单
liquid
反应适用性
reaction type: click chemistry
折射率
n20/D 1.385
密度
1.328 g/mL at 25 °C
SMILES字符串
O=S(F)(C=C)=O
InChI
1S/C2H3FO2S/c1-2-6(3,4)5/h2H,1H2
InChI key
BYPHZHGVWNKAFC-UHFFFAOYSA-N
一般描述
乙烯磺酰氟是一种Michael 受体，用于染料、功能材料、光阻材料、润滑油添加剂和医药化学。它在SuFEx点击化学和有机合成中具有良好的反应活性。
应用
乙烯磺酰氟可用作合成以下物质的反应物：
- β-通过与芳香四氟硼酸重氮盐（arenediazonium tetrafluoroborate）的乙酸钯（II）催化Heck-Matsuda反应制备的芳基乙烯磺酰氟
- 通过与胺/苯胺的Michael加成反应制备的二烷基磺酰基氟（BSF）单体。BSF单体适用于多磺酸盐合成。
- 通过与吡啶酮或异喹啉酮的光催化[2 + 2]环加成制备的环丁烷稠合吡啶基磺酰基氟。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
104.0 °F - closed cup
闪点(°C)
40 °C - closed cup
法规信息
危险化学品
Bruno A da S Dantas et al.
Revista brasileira de psiquiatria (Sao Paulo, Brazil : 1999), 42(2), 201-208 (2019-12-12)
To evaluate the impact of multidimensional interventions on quality of life (QoL) and depressive symptoms in Brazilian older adults living in the community. Longitudinal, quasi-experimental study of older adults receiving conventional primary health care (PHC). The interventions were designed in
Christin Völkner et al.
Stem cell research, 50, 102127-102127 (2020-12-29)
Niemann-Pick disease Type C (NPC) is a rare progressive neurodegenerative disorder with an incidence of 1:120,000 caused by mutations in the NPC1 or NPC2 gene leading to a massive cholesterol accumulation. Here, we describe the generation of induced pluripotent stem
Markus Wolfien et al.
EBioMedicine, 57, 102862-102862 (2020-07-07)
Bone marrow stem cell clonal dysfunction by somatic mutation is suspected to affect post-infarction myocardial regeneration after coronary bypass surgery (CABG). Transcriptome and variant expression analysis was studied in the phase 3 PERFECT trial post myocardial infarction CABG and CD133+
Monika Zouharova et al.
International journal of molecular sciences, 20(18) (2019-09-12)
Transient receptor potential (TRPs) channels are crucial downstream targets of calcium signalling cascades. They can be modulated either by calcium itself and/or by calcium-binding proteins (CBPs). Intracellular messengers usually interact with binding domains present at the most variable TRP regions-N-
Ci Ji Lim et al.
Nature communications, 8(1), 1075-1075 (2017-10-24)
The human shelterin proteins associate with telomeric DNA to confer telomere protection and length regulation. They are thought to form higher-order protein complexes for their functions, but studies of shelterin proteins have been mostly limited to pairs of proteins. Here
商品
In collaboration with K. Barry Sharpless and coworkers, we offer a variety of sulfonyl fluoride reagents that undergo a “Click II” reaction.
在与K. Barry Sharpless及其同事合作后，Sigma-Aldrich现可提供各种磺酰氟试剂，这些试剂经历了“Click II”反应。
相关内容
The Sharpless Lab pursues useful new reactivity and general methods for selectively controlling chemical reactions.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门