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Merck
CN

716731

Sigma-Aldrich

二甲基亚砜-d 6

"Special HOH", ≥99.9 atom % D

别名:

DMSO-d6, 二甲基亚砜-d6, 氘代二甲亚砜

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About This Item

线性分子式:
(CD3)2SO
CAS号:
分子量:
84.17
Beilstein:
1237248
EC 号:
MDL编号:
UNSPSC代码:
12142201
PubChem化学物质编号:
NACRES:
NA.21

蒸汽压

0.42 mmHg ( 20 °C)

质量水平

同位素纯度

≥99.9 atom % D

方案

≥99% (CP)

表单

liquid

自燃温度

573 °F

expl. lim.

42 %

技术

NMR: suitable

折射率

n20/D 1.476 (lit.)

沸点

189 °C (lit.)

mp

20.2 °C (lit.)

密度

1.190 g/mL at 25 °C (lit.)

质量偏移

M+6

SMILES字符串

[2H]C([2H])([2H])S(=O)C([2H])([2H])[2H]

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3/i1D3,2D3

InChI key

IAZDPXIOMUYVGZ-WFGJKAKNSA-N

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一般描述

Dimethyl sulfoxide-d6 (DMSO-d6) is a deuterated NMR solvent. It undergoes photodissociation to generate CD3 radical photoproducts, which have been analyzed by infrared diode laserabsorption spectroscopy. Dissociation dynamics of DMSO-d6 at 193nm was examined using photo fragment translational spectroscopy method.

应用

Dimethyl sulfoxide-d6 may be used as an NMR solvent for 1H and 13C NMR experiments.

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储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

190.4 °F

闪点(°C)

88 °C


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Solution forms of an antitumor cyclic hexapeptide, RA-VII in dimethyl sulfoxide-d6 from nuclear magnetic resonance studies.
Itokawa H, et al.
Chemical & Pharmaceutical Bulletin, 40(4), 1050-1052 (1992)
Unraveling the dissociation of dimethyl sulfoxide following absorption at 193 nm.
Blank DA, et al.
J. Chem. Phys. , 106(2), 539-550 (1997)
Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of dimethyl sulfoxide-d6.
Rudolph RN, et al.
J. Chem. Phys. , 106(4), 1346-1352 (1997)
Priya P Netalkar et al.
European journal of medicinal chemistry, 79, 47-56 (2014-04-12)
Air and moisture stable coordination compounds of late first row transition metals, viz. Co(II), Ni(II), Cu(II) and Zn(II), with a newly designed ligand, 2-(2-benzo[d]thiazol-2-yl)hydrazono)propan-1-ol (LH), were prepared and successfully characterized using various spectro-analytical techniques. The molecular structures of the ligand
Barbara Parrino et al.
European journal of medicinal chemistry, 94, 367-377 (2015-03-18)
Three new ring systems, pyrido[2',3':3,4]pyrrolo[1,2-a]quinoxalines, pyrido[3',2':3,4]pyrrolo[1,2-a]quinoxalines and pyrido[2',3':5,6]pyrazino[2,1-a]isoindoles, were synthesized through an aza-substitution on the already active isoindolo-quinoxaline system and in particular in the position 7 or 4 of the isoindole moiety and in position 5 of the quinoxaline portion.

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