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Merck
CN

688738

Sigma-Aldrich

Basolite® A100

greener alternative

produced by BASF

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别名:
MIL-53(Al), 对苯二甲酸铝
经验公式(希尔记法):
C8H5AlO5
分子量:
208.10
UNSPSC代码:
26111700
NACRES:
NA.23

等级

produced by BASF

质量水平

形式

tablet

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

表面积

1100-1500 m2/g

粒径分布

31.55 μm (D50)

堆积密度

0.4 g/cm3

环保替代产品分类

一般描述

Basolite (TM) A100 也称为 MIL-53 (Al)。它是一种超微孔金属骨架 (MOF)。
Basolite®A100是一种微孔金属有机框架(MOF),由微孔直径可达900 pm的3D网络组成。由于其包含通过1,4-苯二甲酸二甲酯配体连接的八面体AlO4(OH)2单元,因此具有与MIL-53(Al)相同的特性。它可以形成一个比表面积高达1084 2g-1 的框架,孔容约为0.51 cm2g-1
我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了能源效率。点击此处,查看更多详情。

应用

Basolite®A100主要用于CO2/CH4和CO2/N2的二元气体分离。还可用于气体吸附(氢气)和CO2的超临界吸附。
采用 Basolite (TM) A100 分离 C8-烷基芳香族化合物。

其他说明

可在 200°C(真空)下重新激活

法律信息

Basolite is a registered trademark of BASF SE

象形图

Health hazardExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Irrit. 2 - Repr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


分析证书(COA)

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Pure and mixed gas adsorption of CH 4 and N 2 on the metal-organic framework Basolite A100 and a novel copper-based 1, 2, 4-triazolyl isophthalate MOF
Mollmer J, et al.
Journal of Materials Chemistry, 22(20), 10274-10286 (2012)
Gérard Férey et al.
Chemical communications (Cambridge, England), (24), 2976-2977 (2004-01-06)
Hydrogen adsorption has been studied in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+); these solids show a hydrogen storage capacity of 3.8 and 3.1 wt.% respectively when loaded at 77 K under 1.6 MPa.
A complete procedure for acidic gas separation by adsorption on MIL-53 (Al)
Heymans N, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 154(1), 93-99 (2012)
Christian Serre et al.
Journal of the American Chemical Society, 124(45), 13519-13526 (2002-11-07)
The first three-dimensional chromium(III) dicarboxylate, MIL-53as or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)].[HO(2)C-C(6)H(4)-CO(2)H](0.75), has been obtained under hydrothermal conditions (as: as-synthesized). The free acid can be removed by calcination giving the resulting solid, MIL-53ht or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)]. At room temperature, MIL-53ht adsorbs
A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(1), 34-42 (2013)

商品

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

金属有机骨架(MOF)是一类相对较新的多孔晶体材料,具有广泛的应用范围。MOF由充当接合处的金属离子或簇组成,并由多向有机配体所结合,而其在网络结构中作为接头。

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