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质量水平
形式
solid
反应适用性
core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization
mp
143.5-148.5 °C
储存温度
2-8°C
SMILES字符串
CC1=CC(C)=CC(C)=C1N2CCN(C3=C(C)C=C(C)C=C3C)C2=[Ru](Cl)(Cl)=CC4=CC=CC=C4.P(C5CCCCC5)(C6CCCCC6)C7CCCCC7
InChI
1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
InChI key
FCDPQMAOJARMTG-UHFFFAOYSA-L
应用
可用作催化剂：
- 通过RCM反应从酚类化合物合成香豆素。
- 裂解(E)-烯丙基vic-二醇成乙醛。
了解更多复分解催化剂
法律信息
产品许可证
该产品及其制造或使用受Umicore PMC拥有或控制的一项或多项已发布或正在申请的美国专利（和国外等同专利）权限管辖。通过Sigma-Aldrich、其关联公司或其授权分销商从Umicore PMC购买此产品，购买者将享受有限的一次性、非排他、不可转让、不可分配的许可。购买者使用此产品可能会侵犯第三方拥有或控制的专利。购买者应自行确保其使用产品未侵犯第三方专利权或超出本协议授予的许可范围。
有关产品的更多信息，请询当地Umicore PMC联系人，网址http://www.pmc.umicore.com。
警示用语：
Warning
危险声明
危险分类
Flam. Sol. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.
How do I get lot-specific information or a Certificate of Analysis?
The lot specific COA document can be found by entering the lot number above under the "Documents" section.
What benefits does Product 569747, Grubbs Catalyst, 2nd Generation, have over other olefin metathesis catalysts?
Grubbs' Catalysts are extraordinarily versatile. They tolerate other functional groups in the alkene and are compatible with a wide range of solvents.
What types of reactions is Product 569747, Grubbs Catalyst, 2nd Generation, used in?
It is often used in organic synthesis to achieve olefin cross-metathesis, ring-opening metathesis polymerization (ROMP), and ring-closing metathesis.
What is the difference between the First and Second Generation Grubbs Catalyst?
The Second Generation Catalyst has the same uses in organic synthesis as the First Generation Catalyst, but it has a higher activity.
How do I order larger quantities of Product 569747, Grubbs Catalyst, 2nd Generation?
Commercial quantities are available directly from Materia. Their phone number is 626-584-8400, or their e-mail address is info@materia-inc.com.
Is it necessary to handle Product 569747, Grubbs Catalyst, 2nd Generation, under inert atmosphere?
The Grubbs Catalyst is air sensitive. Therefore, we do recommend to handle and store under nitrogen atmosphere.
How do I find price and availability?
There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote. USA customers: 1-800-325-3010 or view local office numbers.
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
My question is not addressed here, how can I contact Technical Service for assistance?
Ask a Scientist here.
商品
Learn tips and tricks for how to properly use inhibitors including how to select the right inhibitor and how to plan experiments with inhibitors.
实验方案
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
相关内容
Research in the Grubbs group has centered on the development and application of a suite of highly active, selective, and bench stable ruthenium alkylidene complexes capable of catalyzing versatile olefin metatheses.
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