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Merck
CN

224367

Sigma-Aldrich

双(三甲基硅基)氨基锂 溶液

1.0 M in hexanes

别名:

六甲基二硅氮烷 锂盐

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About This Item

线性分子式:
[(CH3)3Si]2NLi
CAS号:
分子量:
167.33
Beilstein:
3567910
MDL编号:
UNSPSC代码:
12352111
PubChem化学物质编号:
NACRES:
NA.22

形式

liquid

质量水平

浓度

1.0 M in hexanes

bp

55-56 °C

密度

0.707 g/mL at 25 °C

SMILES字符串

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

YNESATAKKCNGOF-UHFFFAOYSA-N

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应用

与铑(I)催化共同作用可显著加快苯乙炔的聚合反应。

警示用语:

Danger

危险分类

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3

靶器官

Central nervous system, Nervous system

补充剂危害

WGK

WGK 3

闪点(°F)

-23.8 °F

闪点(°C)

-31 °C

个人防护装备

Faceshields, Gloves, Goggles

法规信息

危险化学品

分析证书(COA)

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Macromolecules, 39, 5347-5347 (2006)
A Sebok et al.
Journal of chromatography. A, 1211(1-2), 104-112 (2008-10-14)
This paper presents a derivatization, mass fragmentation study relating to the most common six cholic acids, such as cholic, lithocholic, chenodeoxycholic, ursodeoxycholic, 3-hydroxy,7-ketocholanic and dehydrocholic acids, identified and quantified as pollutants in the aquatic environment at the first time. Derivatizations
Hexamethyldisilazane-mediated controlled polymerization of alpha-amino acid N-carboxyanhydrides.
Hua Lu et al.
Journal of the American Chemical Society, 129(46), 14114-14115 (2007-10-30)
Daniele Fabbri et al.
Environmental science & technology, 42(8), 2957-2963 (2008-05-24)
Using the pyrolysis-gas chromatography-mass spectrometry and off-line pyrolysis/silylation methods for lignites from three Miocene brown coal basins of Poland resulted in the characterization of many organic compounds, including dominant cellulose degradation products such as levoglucosan, 1,6-anhydro-beta-D-glucofuranose, and 1,4:3,6-dianhydroglucopyranose. Levoglucosan is
Jerry Isaacson et al.
Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)
(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an

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