187054
4-溴苄醇
99%
别名:
(4-溴苯基)甲醇, (对溴苯基)甲醇, 1-(对溴苯基)甲醇, 1-溴-4-(羟甲基)苯, 4-羟甲基-1-溴苯, 对溴苯甲醇
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关于此项目
线性分子式:
BrC6H4CH2OH
化学文摘社编号:
分子量:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-851-7
Beilstein/REAXYS Number:
1931620
MDL number:
产品名称
4-溴苄醇, 99%
InChI key
VEDDBHYQWFOITD-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
SMILES string
OCc1ccc(Br)cc1
assay
99%
form
solid
mp
75-77 °C (lit.)
solubility
dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow
functional group
bromo
hydroxyl
Quality Level
Gene Information
human ... ALOX12(239), ALOX15(246)
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Application
使用 4-溴苄醇合成：
- 羟基末端功能化、取代聚芴
- 聚（9,9-二十二烷基芴-2,7-二基）和聚（甲基丙烯酸羟乙酯）的三嵌段共聚物，对称棒状线圈
General description
4-溴苯甲醇与乙酰基二茂铁和芳基硼酸发生三组分反应，生成含有联芳基的二茂铁酮 。它在聚乙烯聚吡咯烷酮负载的过氧化氢、二氧化硅硫酸和溴化铵存在下发生氧化反应，生成 4-溴苯甲醛 。它与 1,1,1,3,3,3-六甲基二硅氮烷在催化剂量的天冬氨酸乙腈溶液中发生有效的三甲基硅烷化反应 。
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 3
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Qianyan Li et al.
International journal of nanomedicine, 15, 4825-4845 (2020-08-06)
Nanosized drug delivery systems (NDDSs) have shown excellent prospects in tumor therapy. However, insufficient penetration of NDDSs has significantly impeded their development due to physiological instability and low passive penetration efficiency. Herein, we prepared a core cross-linked pullulan-modified nanosized system
Synthesis of an Amphiphilic p-Conjugated Triblock Copolymer of Poly (9, 9-didodecylfluorene-2, 7-diyl) and Poly (hydroxyl ethyl methacrylate).
Kim HJ, et al.
Macromolecular Research, 13(6), 529-532 (2005)
I M Russu et al.
Biochemistry, 25(4), 808-815 (1986-02-25)
High-resolution proton nuclear magnetic resonance spectroscopy and relaxation techniques have been used to investigate the interactions of sickle cell hemoglobin (Hb S) and human normal adult hemoglobin (Hb A) with p-bromobenzyl alcohol, L-phenylalanine, L-tryptophan, and L-valine. With the exception of
C Ho et al.
Progress in clinical and biological research, 240, 59-66 (1987-01-01)
Two new techniques of nuclear magnetic resonance spectroscopy are proposed to identify and characterize the binding sites of antisickling compounds to Hb S: measurements of the longitudinal relaxation rates (T1(-1)) of the C2 protons of individual surface histidyl residues of
Yoshihiro Kon et al.
Organic & biomolecular chemistry, 19(5), 1115-1121 (2021-01-14)
The oxidation of alcohols to aldehydes is a powerful reaction pathway for obtaining valuable fine chemicals used in pharmaceuticals and biologically active compounds. Although many oxidants can oxidize alcohols, only a few hydrogen peroxide oxidations can be employed to continuously
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