质量水平
检测方案
97%
形式
solid
杂质
≤3% 1-bromonaphthalene
bp
281-282 °C (lit.)
mp
52-55 °C (lit.)
溶解性
methanol: soluble 50 mg/mL, clear, colorless to yellow
SMILES字符串
Brc1ccc2ccccc2c1
InChI
1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
InChI key
APSMUYYLXZULMS-UHFFFAOYSA-N
基因信息
human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)
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一般描述
2-溴萘与氰化亚铜在 N-甲基吡咯烷酮中的反应已有研究。 2-溴萘在甲醇溶剂中的T1→Tn转变的纳秒时间分辨共振拉曼光谱已有研究。
应用
在微波辐射下，2-溴萘在水中通过Suzuki交叉偶联反应可用于合成联芳。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2
WGK
WGK 3
闪点(°F)
235.4 °F
闪点(°C)
113 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Rapid microwave-promoted Suzuki cross coupling reaction in water.
Bai L, et al.
Green Chemistry, 5(5), 615-617 (2003)
Nanosecond time-resolved resonance Raman investigation of the T1→ Tn transition of 2-bromonaphthalene.
Shoute LCT, et al.
Chemical Physics Letters, 290(1), 24-28 (1998)
Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.
Sheehan J, et al.
The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)
J M Shoulder et al.
SAR and QSAR in environmental research, 30(4), 229-245 (2019-03-22)
Persistent organic contaminants in the environment pose an environmental risk due to widespread occurrence and toxic properties. Advanced oxidation processes (AOPs) are treatment methods that have been used to successfully degrade organic contaminants in water, soil, sediments and sludge. Reaction
Isaiah R Speight et al.
Molecules (Basel, Switzerland), 25(3) (2020-02-06)
Owing to the strength of the C-F bond, the 'direct' preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods
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