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Merck
CN

183644

Sigma-Aldrich

2-溴萘

97%

别名:

β-溴萘, β-萘基溴, 2-萘基溴

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About This Item

经验公式(希尔记法):
C10H7Br
CAS号:
分子量:
207.07
Beilstein:
1858110
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

solid

杂质

≤3% 1-bromonaphthalene

沸点

281-282 °C (lit.)

mp

52-55 °C (lit.)

溶解性

methanol: soluble 50 mg/mL, clear, colorless to yellow

官能团

bromo

SMILES字符串

Brc1ccc2ccccc2c1

InChI

1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H

InChI key

APSMUYYLXZULMS-UHFFFAOYSA-N

基因信息

human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)

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一般描述

2-溴萘与氰化亚铜在 N-甲基吡咯烷酮中的反应已有研究。 2-溴萘在甲醇溶剂中的T1→Tn转变的纳秒时间分辨共振拉曼光谱已有研究

应用

在微波辐射下,2-溴萘在水中通过Suzuki交叉偶联反应可用于合成联芳

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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Rapid microwave-promoted Suzuki cross coupling reaction in water.
Bai L, et al.
Green Chemistry, 5(5), 615-617 (2003)
Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.
Sheehan J, et al.
The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)
Isaiah R Speight et al.
Molecules (Basel, Switzerland), 25(3) (2020-02-06)
Owing to the strength of the C-F bond, the 'direct' preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods
Nanosecond time-resolved resonance Raman investigation of the T1→ Tn transition of 2-bromonaphthalene.
Shoute LCT, et al.
Chemical Physics Letters, 290(1), 24-28 (1998)
J M Shoulder et al.
SAR and QSAR in environmental research, 30(4), 229-245 (2019-03-22)
Persistent organic contaminants in the environment pose an environmental risk due to widespread occurrence and toxic properties. Advanced oxidation processes (AOPs) are treatment methods that have been used to successfully degrade organic contaminants in water, soil, sediments and sludge. Reaction

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