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Merck
CN

131652

吡啶 N-氧化物

95%

别名:

Pyridine oxide

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关于此项目

经验公式(希尔记法):
C5H5NO
化学文摘社编号:
分子量:
95.10
Beilstein:
105257
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

95%

表单

solid

沸点

270 °C (lit.)

mp

62-67 °C (lit.)

SMILES字符串

[O-][n+]1ccccc1

InChI

1S/C5H5NO/c7-6-4-2-1-3-5-6/h1-5H

InChI key

ILVXOBCQQYKLDS-UHFFFAOYSA-N

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一般描述

具有[2]轮烷的吡啶N-氧化物轴通过阴离子模板化穿线 - 后续 - 加塞策略合成

应用

吡啶N-氧化物用于研究吡啶N-氧化物在乙腈中的FTIR光谱

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

289.4 °F - closed cup

闪点(°C)

143 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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G Pitsevich et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 120, 585-594 (2014-01-01)
FTIR spectra of pyridine N-oxide and trichloroacetic acid H-bonded complex in acetonitrile were studied at 20 and 50°C. The calculations of equilibrium configurations of the complex and their IR spectra in harmonic- and anharmonic approximations were carried out at the
Highly efficient gold nanoparticle catalyzed deoxygenation of amides, sulfoxides, and pyridine N-oxides.
Yusuke Mikami et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(6), 1768-1772 (2011-01-29)
Jan Balzarini et al.
The Journal of antimicrobial chemotherapy, 55(2), 135-138 (2005-01-15)
Pyridine N-oxide derivatives represent a new class of anti-HIV compounds, for which some members exclusively act through inhibition of HIV-1 reverse transcriptase and thus characteristically behave as non-nucleoside reverse transcriptase inhibitors. Other members act, additionally or alternatively, at a post-integrational
Jinshui Chen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(30), 7268-7276 (2009-07-07)
Optically active chiral alkyl chlorides are valuable compounds because of their bioactivity and versatile synthetic utility. Accordingly, the ring opening of epoxides with a chloride nucleophile stands as an important goal in asymmetric catalysis. We describe herein recent advances in
Masahito Murai et al.
Chemical communications (Cambridge, England), 48(61), 7622-7624 (2012-06-26)
Gold(I)-catalysed tandem oxygen-transfer/cycloisomerisation reaction of 2-(2-propynyl)pyridine N-oxides provides an atom-economical route to indolizinone frameworks.

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