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  • High-Concentration Aqueous Dispersions of Nanoscale 2D Materials Using Nonionic, Biocompatible Block Copolymers.

High-Concentration Aqueous Dispersions of Nanoscale 2D Materials Using Nonionic, Biocompatible Block Copolymers.

Small (Weinheim an der Bergstrasse, Germany) (2015-12-01)
Nikhita D Mansukhani, Linda M Guiney, Peter J Kim, Yichao Zhao, Diego Alducin, Arturo Ponce, Eduardo Larios, Miguel Jose Yacaman, Mark C Hersam
ABSTRACT

Conditions for the dispersion of molybdenum disulfide (MoS2) in aqueous solution at concentrations up to 0.12 mg mL(-1) using a range of nonionic, biocompatible block copolymers (i.e., Pluronics and Tetronics) are identified. Furthermore, the optimal Pluronic dispersant for MoS2 is found to be effective for a range of other 2D materials such as molybdenum diselenide, tungsten diselenide, tungsten disulfide, tin selenide, and boron nitride.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tungsten (IV) diselenide, lithium intercalated
Sigma-Aldrich
Tungsten (IV) disulfide, lithium intercalated
Sigma-Aldrich
Molybdenum disulfide suspension
Sigma-Aldrich
Tungsten disulfide suspension
Sigma-Aldrich
Molybdenum disulfide, dispersion, 0.1-0.5 mg/mL in H2O
Sigma-Aldrich
Molybdenum disulfide nanoplatelets
Sigma-Aldrich
Tungsten disulfide nanoplatelets, 50-300 nm, thickness < 3 layers, powder
Sigma-Aldrich
Tungsten disulfide suspension
Sigma-Aldrich
Molybdenum (IV) diselenide, lithium intercalated
Sigma-Aldrich
Molybdenum disulfide suspension, avg. no. of layers, < 3