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  • C-H activation/borylation/oxidation: a one-pot unified route to meta-substituted phenols bearing ortho-/para-directing groups.

C-H activation/borylation/oxidation: a one-pot unified route to meta-substituted phenols bearing ortho-/para-directing groups.

Journal of the American Chemical Society (2003-06-26)
Robert E Maleczka, Feng Shi, Daniel Holmes, Milton R Smith
PMID12822984
ABSTRACT

An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.

MATERIALS
Product Number
Brand
Product Description
685062
Sigma-Aldrich
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Sign Into View Organizational & Contract Pricing
SKUPack SizeAvailabilityPriceQuantity
1 mL
Estimated to ship on 2025年4月21日
Details...
¥1,655.26