- Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.
Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.
The Journal of organic chemistry (2007-10-16)
Jumreang Tummatorn, Philip A Albiniak, Gregory B Dudley
PMID17935354
ABSTRACT
Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) and carboxylic acids. Alcohols, phenols, amides, and other sensitive functionality are not affected; a dual role for Et3N as a promoter and a scavenger is postulated. Benzyl esters are obtained from substrates including amino acid and sugar derivatives.
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