Skip to Content
Merck
CN
  • A new class of C1-symmetric monosulfoximine ligands for enantioselective hetero Diels-Alder reactions.

A new class of C1-symmetric monosulfoximine ligands for enantioselective hetero Diels-Alder reactions.

Chemical communications (Cambridge, England) (2003-12-04)
Carsten Bolm, Marinella Verrucci, Oliver Simic, Pier Giorgio Cozzi, Gerhard Raabe, Hiroaki Okamura
PMID14651124
ABSTRACT

Quinoline-based C1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee.