- Scalable synthesis of quaterrylene: solution-phase 1H NMR spectroscopy of its oxidative dication.
Scalable synthesis of quaterrylene: solution-phase 1H NMR spectroscopy of its oxidative dication.
Chemical communications (Cambridge, England) (2013-09-04)
Rajesh Thamatam, Sarah L Skraba, Richard P Johnson
PMID23999880
ABSTRACT
Quaterrylene is prepared in a single reaction and high yield by Scholl-type coupling of perylene, utilizing trifluoromethanesulfonic acid as catalyst and DDQ or molecular oxygen as oxidant. Dissolution in 1 M triflic acid/dichloroethane with sonication yields the aromatic quaterrylene oxidative dication, which is characterized by its (1)H NMR spectrum.
MATERIALS