Review on palladium-containing perovskites: synthesis, physico-chemical properties and applications in catalysis.

Review on palladium-containing perovskites: synthesis, physico-chemical properties and applications in catalysis.

Journal of nanoscience and nanotechnology (2014-04-23)

Abdellatif Essoumhi, Saïd El Kazzouli, Mosto Bousmina

ABSTRACT

This review reports on the recent advances in the synthesis and physico-chemical properties of palladium-containing perovskites. Initially, the perovskite structure is briefly reviewed, then palladium-containing perovskites synthesis and physico-chemical properties are detailed. The applications of palladium-containing perovskites in catalysis; namely, NO reduction, methane combustion, methanol as well as ethanol oxidation, are briefly highlighted. The involvement and the important contribution of palladium-containing perovskites in cross-coupling reactions, especially Suzuki-Miyaura, Sonogashira, Ulmann and Grignard, are discussed.

MATERIALS

Product Number

Brand

Product Description

326666

Sigma-Aldrich

Palladium, powder, <1 μm, ≥99.9% trace metals basis

203939

Sigma-Aldrich

Palladium, powder, 99.995% trace metals basis

203998

Sigma-Aldrich

Palladium, powder or granules, 99.99% trace metals basis

464651

Sigma-Aldrich

Palladium, powder, <75 μm, 99.9% trace metals basis

348694

Sigma-Aldrich

Palladium, wire, diam. 0.5 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

287474

Sigma-Aldrich

Palladium, foil, thickness 0.5 mm, 99.9% trace metals basis

686468

Sigma-Aldrich

Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

GF99541985

Palladium, tube, 200mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF99300371

Palladium, wire reel, 50m, diameter 0.125mm, hard, 99.95%

GF90203475

Palladium, foil, not light tested, 25x25mm, thickness 0.0025mm, 99.95%

GF71618193

Palladium, wire reel, 5m, diameter 0.025mm, as drawn, 99.9%

GF68272588

Palladium, rod, 25mm, diameter 6.0mm, 99.95%

GF88212898

Palladium, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99.95%

GF71407650

Palladium, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%

GF89451489

Palladium, rod, 50mm, diameter 2.0mm, 99.95%

GF94758991

Palladium, foil, light tested, 50x50mm, thickness 0.047mm, as rolled, 99.95%

GF73243717

Palladium, foil, not light tested, 25x25mm, thickness 0.004mm, 99.95%

GF88744843

Palladium, wire reel, 1m, diameter 0.02mm, as drawn, 99.95%

GF99402510

Palladium, microfoil, disks, 50mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF99771261

Palladium, wire reel, 0.5m, diameter 0.25mm, as drawn, 99.99+%

GF96794409

Palladium, wire reel, 25m, diameter 0.125mm, hard, 99.95%

GF92472688

Palladium, wire reel, 0.2m, diameter 1.0mm, hard, 99.95%

GF70629880

Palladium, foil, not light tested, 50x50mm, thickness 0.003mm, 99.95%

GF90054659

Palladium, rod, 50mm, diameter 6.0mm, 99.95%

GF75251909

Palladium, microfoil, disks, 10mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF85707513

Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%

GF96040111

Palladium, foil, not light tested, 50x50mm, thickness 0.004mm, 99.95%

GF73143491

Palladium, foil, not light tested, 25x25mm, thickness 0.0125mm, 99.95%