sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

GF83400364

Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF54583016

Nickel, rod, 50mm, diameter 25.4mm, 99.99+%

GF63510308

Nickel, foil, 10mm disks, thickness 0.125mm, as rolled, 100%

GF68355085

Nickel, rod, 200mm, diameter 1.5mm, 99.99+%

GF84148397

Nickel, foil, 1m coil, thickness 0.075mm, annealed, 99%

GF95866824

Nickel, rod, 200mm, diameter 30mm, 99%

GF85580983

Nickel, tube, 100mm, outside diameter 2.5mm, inside diameter 2.25mm, wall thickness 0.125mm, hard, 99.5%

GF67821543

Nickel, rod, 500mm, diameter 20.0mm, 99%

GF15634054

Nickel, rod, 500mm, diameter 9.5mm, 99%

GF85929069

Nickel, tube, 1000mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%

GF03591110

Nickel, foil, 1m coil, thickness 0.038mm, 99.9%

GF68841535

Nickel, foil, 10mm disks, thickness 0.20mm, annealed, 99%

GF12712418

Nickel, foil, 1m coil, thickness 1.0mm, annealed, 99.98%

GF88937162

Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%

GF64818850

Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%

GF88726168

Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%

GF74649695

Nickel, foil, 2m coil, thickness 0.3mm, annealed, 99%

GF20973517

Nickel, foil, 0.5m coil, thickness 0.0125mm, 99.9%

GF93488596

Nickel, foil, 10mm disks, thickness 0.03mm, 99.9%

GF38044627

Nickel, foil, 300x300mm, thickness 0.125mm, annealed, 99%

GF56481969

Nickel, pellets, 20g, max. size 5mm, 99.99+%

GF95071103

Nickel, tube, 500mm, outside diameter 2.8mm, inside diameter 1.8mm, wall thickness 0.5mm, hard, 99.5%

GF73011833

Nickel, foil, 50x50mm, thickness 1.0mm, annealed, 99.98%

GF18019144

Nickel, foil, 50x50mm, thickness 1.0mm, as rolled, 99.999%

GF43379253

Nickel, foil, 25x25mm, thickness 0.30mm, as rolled, 99.98%