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  • Palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.

Palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.

Chemical communications (Cambridge, England) (2003-11-01)
Naofumi Tsukada, Tetsuo Sato, Yoshio Inoue
ABSTRACT

Various allylic alcohols reacted with n-butyl acrylate in the presence of p-toluenesulfonic anhydride and palladium catalysts to yield the corresponding n-butyl 2,5-dienoates with high regioselectivity.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
p-Toluenesulfonic anhydride, 97%