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  • Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin.

Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin.

Chemical communications (Cambridge, England) (2011-05-05)
Barry C Pemberton, Raushan K Singh, Alexander C Johnson, Steffen Jockusch, José P Da Silva, Angel Ugrinov, Nicholas J Turro, D K Srivastava, J Sivaguru
ABSTRACT

Guest induced shape change of the cucurbit[8]uril cavity is likely rate limiting in the supramolecular photocatalytic cycle for CB8 mediated photodimerization of 6-methylcoumarin.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
6-Methylcoumarin, ≥99%, FCC, FG
Sigma-Aldrich
6-Methylcoumarin, ≥99%