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  • Enzymatic synthesis of p-nitrophenyl N,N',N'',N'',N''''-pentaacetyl-beta-chitopentaoside in water-methanol system; significance as a substrate for lysozyme assay.

Enzymatic synthesis of p-nitrophenyl N,N',N'',N'',N''''-pentaacetyl-beta-chitopentaoside in water-methanol system; significance as a substrate for lysozyme assay.

Biochimica et biophysica acta (1988-03-23)
T Usui, Y Hayashi, F Nanjo, Y Ishido
ABSTRACT

Transchitooligosylation from (GlcNAc)5 to the 4-position of PNP-GlcNAc was efficiently induced through lysozyme catalysis in an aqueous solution containing methanol with a high concentration. Use of the aqueous methanol system in this reaction not only guaranteed solubility of PNP-GlcNAc substrate, but also resulted in a remarkable increase in PNP-(GlcNAc)5 production. PNP-(GlcNAc)5 was substrate for lysozyme assay compared with PNP-(GlcNAc)4.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
4-Nitrophenyl N-acetyl-α-D-glucosaminide, ≥98%
Sigma-Aldrich
4-Nitrophenyl N-acetyl-β-D-glucosaminide, ≥99% (TLC)