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  • A general palladium-catalyzed carbonylative synthesis of 2-alkylbenzoxazinones from 2-bromoanilines and acid anhydrides.

A general palladium-catalyzed carbonylative synthesis of 2-alkylbenzoxazinones from 2-bromoanilines and acid anhydrides.

Chemistry (Weinheim an der Bergstrasse, Germany) (2012-09-05)
Xiao-Feng Wu, Helfried Neumann, Matthias Beller
ABSTRACT

(C), its (O)K! An efficient palladium-catalyzed carbonylative synthesis of 2-alkylbenzoxazinones has been developed. By starting from 2-bromoanilines and acid anhydrides, the corresponding products were isolated in good yields.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
3-Bromoaniline, 98%