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  • Green determination of the presence of volatile organic compounds in vehicle repair shops through passive sampling.

Green determination of the presence of volatile organic compounds in vehicle repair shops through passive sampling.

Talanta (2012-09-04)
Daniel Sanjuán-Herráez, Isabel Lliso, Agustín Pastor, Miguel de la Guardia
ABSTRACT

A simple, fast and green direct analytical methodology has been developed to evaluate the concentration level of volatile organic compounds (VOCs) in indoor areas of vehicle repair shops using membrane devices as passive samplers. VOCs retained in the samplers were directly determined without any sample pre-treatment and avoiding the use of solvents by head space (HS) coupled to gas chromatography-mass spectrometry (GC-MS) in only 20 min. Benzene, toluene, tetrachloroethene, m,p-xylene and o-xylene were found at concentration levels from 0.1 to 11.2 mg m(-3).

MATERIALS
Product Number
Brand
Product Description

Supelco
Tetrachloroethylene, analytical standard
Sigma-Aldrich
Tetrachloroethylene, anhydrous, ≥99%
Sigma-Aldrich
Tetrachloroethylene, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Tetrachloroethylene, ACS reagent, ≥99.0%
Sigma-Aldrich
Tetrachloroethylene, ≥99.5%
Supelco
Density Standard 1623 kg/m3, H&D Fitzgerald Ltd. Quality