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  • Concurrent anion...pi interactions between a perchlorate ion and two pi-acidic aromatic rings, namely pentafluorophenol and 1,3,5-triazine.

Concurrent anion...pi interactions between a perchlorate ion and two pi-acidic aromatic rings, namely pentafluorophenol and 1,3,5-triazine.

Chemical communications (Cambridge, England) (2008-07-18)
Rens J Götz, Arturo Robertazzi, Ilpo Mutikainen, Urho Turpeinen, Patrick Gamez, Jan Reedijk
ABSTRACT

The rational design of a ligand containing two electron-poor pi-rings, i.e. a triazine and a pentafluorophenoxy groups, has allowed the preparation of a copper complex where both the anticipated anion...pi interactions are present.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Pentafluorophenol, ReagentPlus®, ≥99%