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  • Synthesis and photophysics of a porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonding.

Synthesis and photophysics of a porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonding.

Chemical communications (Cambridge, England) (2005-03-30)
Jonathan L Sessler, Janarthanan Jayawickramarajah, Andreas Gouloumis, Tomas Torres, Dirk M Guldi, Stephen Maldonado, Keith J Stevenson
ABSTRACT

A novel porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonds is described; this system undergoes photoinduced electron transfer upon irradiation with visible light to produce a charge separated state that is substantially longer lived than that of previous dyads of this type.

MATERIALS
Product Number
Brand
Product Description

Supelco
N-Methylaniline, analytical standard
Sigma-Aldrich
N-Methylaniline, 98%
Sigma-Aldrich
N-Methylaniline, ≥99%
Sigma-Aldrich
N-Methylaniline, purum, ≥98.0% (GC)