- Protoboration of Alkynes and Miyaura Borylation Catalyzed by Low Loadings of Palladium.
Protoboration of Alkynes and Miyaura Borylation Catalyzed by Low Loadings of Palladium.
The Journal of organic chemistry (2022-10-13)
Lei Xu, Zheng Dong, Qi Zhang, Ning Deng, Shi-Yu Li, Hua-Jian Xu
PMID36223839
ABSTRACT
The versions of Miyaura borylation and protoboration of alkynes catalyzed by low loadings of palladium (400 mol ppm = 0.04 mol %) have been developed. These transformations have a broad substrate scope, good functional-group compatibility, and gram-scale synthetic ability.
MATERIALS