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Merck
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Formic acid 98% - 100% for LC-MS LiChropur™
Supelco
5.33002
Formic acid 98% - 100%
Formic acid 98 - 100% for HPLC LiChropur™
Supelco
5.43804
Formic acid 98 - 100%
Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur
Supelco
1.00264
Formic acid 98-100%
Formic acid 98-100 % for analysis EMPARTA® ACS
Supelco
1.93015
Formic acid 98-100 %
for LC-MS LiChropur
for HPLC LiChropur
for analysis EMSURE® ACS,Reag. Ph Eur
for analysis EMPARTA® ACS
43816-10ML
Available to ship on April 21, 2025
Details...
CN¥499.65
43816-10ML
Available to ship on April 21, 2025
Details...
CN¥499.65
43816-10ML
Available to ship on April 21, 2025
Details...
CN¥499.65
43816-10ML
Available to ship on April 21, 2025
Details...
CN¥499.65

Description

Synonyms
Formic acid, Methanoic acid, Formylic acid
Formic acid, Methanoic acid, Formylic acid
Formic acid, Methanoic acid, Formylic acid
Formic acid
CAS Number
Molecular Formula
Linear Formula
: HCOOH
Linear Formula
: HCOOH
Linear Formula
: HCOOH
Linear Formula
: HCOOH
Empirical Formula (Hill Notation)
: CH2O2
Empirical Formula (Hill Notation)
: CH2O2
Empirical Formula (Hill Notation)
: CH2O2
Empirical Formula (Hill Notation)
: CH2O2
Molecular Weight
: 46.03
Molecular Weight
: 46.03
Molecular Weight
: 46.03
Molecular Weight
: 46.03
MDL Number
MFCD00003297
MFCD00003297
MFCD00003297
MFCD00003297
Quality Designations

Properties

reg. compliance:
suitable for FDA C-010.02
reg. compliance:
suitable for FDA C-010.02
reg. compliance:
reg. compliance:
Agency:
suitable for DIN 38407-42
suitable for EPA 1633
suitable for ISO/CEN 15968-2010
Agency:
suitable for DIN 38407-42
suitable for ISO/CEN 15968-2010
Agency:
reag. Ph. Eur.
Agency:
anion traces:
anion traces:
anion traces:
chloride (Cl-): ≤5 ppm
sulfate (SO42-): ≤5 ppm
sulfite (SO32-): ≤10 ppm
anion traces:
Assay:
≥98% (acidimetric)
Assay:
≥98% (alkalimetric)
Assay:
≥98% (alkalimetric)
Assay:
autoignition temp.:
1004 °F
autoignition temp.:
1004 °F
autoignition temp.:
1004 °F
autoignition temp.:
1004 °F
bp:
100-101 °C (lit.)
101 °C/1013 hPa
bp:
100-101 °C (lit.)
101 °C/1013 hPa
bp:
100-101 °C (lit.)
101 °C/1013 hPa
bp:
100-101 °C (lit.)
cation traces:
Al: ≤5.0 ppm
Ca: ≤10 ppm
Cu: ≤1.0 ppm
Fe: ≤5.0 ppm
K: ≤5.0 ppm
Mg: ≤2.0 ppm
NH4+: ≤10 ppm
Na: ≤5.0 ppm
cation traces:
Al: ≤0.05 ppm
Ca: ≤0.20 ppm
Cu: ≤0.020 ppm
Fe: ≤2.0 ppm
K: ≤0.10 ppm
Mg: ≤0.50 ppm
Na: ≤0.50 ppm
cation traces:
Ag: ≤0.020 ppm
Al: ≤0.050 ppm
Ba: ≤0.050 ppm
Be: ≤0.020 ppm
Bi: ≤0.10 ppm
Ca: ≤0.20 ppm
Cd: ≤0.050 ppm
Co: ≤0.020 ppm
Cr: ≤0.050 ppm
Cu: ≤0.020 ppm
Fe: ≤2.0 ppm
Ge: ≤0.050 ppm
K: ≤0.10 ppm
Li: ≤0.020 ppm
Mg: ≤0.50 ppm
Mn: ≤0.050 ppm
Mo: ≤0.020 ppm
NH4+: ≤10 ppm
Na: ≤0.50 ppm
Ni: ≤0.050 ppm
Pb: ≤0.020 ppm
Sr: ≤0.020 ppm
Ti: ≤0.10 ppm
Tl: ≤0.050 ppm
V: ≤0.050 ppm
Zn: ≤0.050 ppm
Zr: ≤0.10 ppm
heavy metals (as Pb): ≤10 ppm
cation traces:
color:
color:
color:
APHA: ≤10
color:
density:
1.22 g/mL at 25 °C (lit.)
density:
1.22 g/mL at 25 °C (lit.)
density:
1.22 g/mL at 25 °C (lit.)
density:
1.22 g/mL at 25 °C (lit.)
expl. lim.:
12-38 % (v/v)
57 %
expl. lim.:
12-38 % (v/v)
57 %
expl. lim.:
12-38 % (v/v)
57 %
expl. lim.:
57 %
impurities:
impurities:
impurities:
≤500 ppm Acetic acid (CH3COOH)
impurities:
InChI:
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI:
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI:
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI:
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI key:
BDAGIHXWWSANSR-UHFFFAOYSA-N
InChI key:
BDAGIHXWWSANSR-UHFFFAOYSA-N
InChI key:
BDAGIHXWWSANSR-UHFFFAOYSA-N
InChI key:
BDAGIHXWWSANSR-UHFFFAOYSA-N
mp:
8.2-8.4 °C (lit.)
mp:
8.2-8.4 °C (lit.)
mp:
8.2-8.4 °C (lit.)
mp:
8.2-8.4 °C (lit.)
pH:
2.2 (20 °C, 10 g/L in H2O)
pH:
2.2 (20 °C, 10 g/L in H2O)
pH:
2.2 (20 °C, 10 g/L in H2O)
pH:
form:
liquid
form:
liquid
form:
liquid
form:
product line:
product line:
product line:
EMSURE®
product line:
refractive index:
n20/D 1.370 (lit.)
refractive index:
n20/D 1.370 (lit.)
refractive index:
n20/D 1.370 (lit.)
refractive index:
n20/D 1.370 (lit.)
evapn. residue:
evapn. residue:
evapn. residue:
≤10 ppm
evapn. residue:
SMILES string:
OC=O
SMILES string:
OC=O
SMILES string:
OC=O
SMILES string:
OC=O
grade:
grade:
grade:
ACS reagent
grade:
ACS reagent
storage temp.:
15-25°C
storage temp.:
15-25°C
storage temp.:
15-25°C
storage temp.:
room temp
technique(s):
LC/MS: suitable
technique(s):
HPLC: suitable
technique(s):
HPLC: suitable
technique(s):
transition temp:
flash point 49.5 °C
transition temp:
flash point 49.5 °C
transition temp:
flash point 49.5 °C
transition temp:
vapor density:
1.6 (vs air)
vapor density:
1.6 (vs air)
vapor density:
1.6 (vs air)
vapor density:
1.6 (vs air)
vapor pressure:
44.8 mmHg ( 20 °C)
vapor pressure:
44.8 mmHg ( 20 °C)
vapor pressure:
44.8 mmHg ( 20 °C)
vapor pressure:
44.8 mmHg ( 20 °C)
Quality Level:
100
Quality Level:
100
Quality Level:
300
Quality Level:

Usage and Safety

Application
Formic acid (FA) 98% - 100% is a mobile phase component used in liquid chromatography − mass spectrometry (LC-MS) system for fatty acid profiling of oil seed crops. It can also be used in the quantitative-qualitative analysis of wheatgrass phenolic compounds.
Formic acid 98–100% can be used as a mobilephase additive for the comparative studies using DAD (Diode Array Detector)detection.

  • Modified QuEChERS method combined with ultra performance liquid chromatography-tandem mass spectrometry for detection of cyclopiazonic acid in feeds: This study demonstrates the use of 98-100% formic acid in a modified QuEChERS method, enhancing the efficiency of toxin detection in animal feeds, crucial for maintaining food safety and environmental health (Peng et al., 2024).

  • Adapting Fabric Phase Sorptive Extraction as an Innovative Multitool for Sample Transfer and Extraction in Pharmacokinetic Analysis Followed by LC-MS Determination of Levofloxacin in Plasma Samples: This study utilizes formic acid in developing advanced extraction methods for pharmacokinetic analysis, critical for drug development and therapeutic monitoring in pharmaceutical research (Ekin Dolaksız et al., 2024).

  • Stability Indicating Method Development and Validation of Glycyrrhizin Using RP-HPLC-DAD: Application to Glycyrrhiza glabra Extract: This research uses formic acid in chromatographic analyses to ensure the stability and quality of herbal medicine compounds, relevant in both pharmaceutical and biotechnological fields (Lyngdoh et al., 2024).

Risk and Safety
Pictograms: GHS02,GHS05,GHS06
FlameCorrosionSkull and crossbones
Signal Word:

Danger

Hazard Statements: H226 - H302 - H314 - H331
Hazard Classifications:

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Supp Hazards: EUH071
Storage Class Code:

3 - Flammable liquids

WGK:

WGK 1

Flash Point(F):

121.1 °F - closed cup

Flash Point(C):

49.5 °C - closed cup

Pictograms: GHS02,GHS05,GHS06
FlameCorrosionSkull and crossbones
Signal Word:

Danger

Hazard Statements: H226 - H302 - H314 - H331
Hazard Classifications:

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Supp Hazards: EUH071
Storage Class Code:

3 - Flammable liquids

WGK:

WGK 1

Flash Point(F):

121.1 °F

Flash Point(C):

49.5 °C

Pictograms: GHS02,GHS05,GHS06
FlameCorrosionSkull and crossbones
Signal Word:

Danger

Hazard Statements: H226 - H302 - H314 - H331
Hazard Classifications:

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Supp Hazards: EUH071
Storage Class Code:

3 - Flammable liquids

WGK:

WGK 1

Flash Point(F):

121.1 °F - closed cup

Flash Point(C):

49.5 °C - closed cup

Pictograms: GHS02,GHS06,GHS05
FlameSkull and crossbonesCorrosion
Signal Word:

Danger

Hazard Statements: H226,H302,H314,H331
Hazard Classifications:

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Supp Hazards: EUH071
WGK:

WGK 1