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E14403

Sigma-Aldrich

Ethyl α-bromoisobutyrate

98%

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Synonym(s):
Ethyl 2-bromo-2-methylpropionate
Linear Formula:
(CH3)2CBrCOOC2H5
CAS Number:
Molecular Weight:
195.05
Beilstein:
1098947
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

liquid

refractive index

n20/D 1.444 (lit.)

bp

65-67 °C/11 mmHg (lit.)

density

1.329 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(C)(C)Br

InChI

1S/C6H11BrO2/c1-4-9-5(8)6(2,3)7/h4H2,1-3H3

InChI key

IOLQWGVDEFWYNP-UHFFFAOYSA-N

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General description

Ethyl α-bromoisobutyrate is an organic bromoester used as an initiator in controlled radical polymerization reactions.

Application

Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3

WGK

WGK 3

Flash Point(F)

140.0 °F

Flash Point(C)

60 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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Articles

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Protocols

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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