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Merck
CN

935646

Sigma-Aldrich

1,3,2-二噁唑噻吩-2,2-二氧化物

greener alternative

≥99%, anhydrous, battery grade

别名:

1,3,2-Dioxathiolane 2,2-dioxide, DTD

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About This Item

经验公式(希尔记法):
C2H4O4S
CAS号:
分子量:
124.12
MDL编号:
UNSPSC代码:
12352005

等级

anhydrous
battery grade

质量水平

方案

≥99%

表单

powder

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

≤750 ppm (H2O)

沸点

231 °C

mp

95-97 °C (lit.)

应用

battery manufacturing

环保替代产品分类

储存温度

2-8°C

SMILES字符串

O=S1(=O)OCCO1

InChI

1S/C2H4O4S/c3-7(4)5-1-2-6-7/h1-2H2

InChI key

ZPFAVCIQZKRBGF-UHFFFAOYSA-N

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一般描述

Ethylene sulfate (DTD) is a polar cyclic sulfate ester. It is a white powder that is soluble in many of the polar organic solvents used in battery applications, including carbonates. Our battery grade ethylene sulfate is differentiated by its high purity, low trace water content, and low trace acid content, which avoid unwanted chemical reactions with the anode and increase capacity, safety, and life span in batteries

应用

Ethylene sulfate has a range of industrial applications. Our anhydrous battery grade ethylene sulfate is primarily used as an electrolyte additive to extend the lifetime of lithium-ion batteries and sodium-ion batteries.[,] Ethylene sulfate helps to improve the formation of a stable solid-electrolyte interphase (SEI) on the surface of the anode material, which can prevent reaction between the anode and the electrolyte, leading to better battery lifespan and more stable impedance across the interphase.[] DTD is often used in conjunction with other additives. One of the best-performing electrolyte formulations for graphite cells is a 1.0 M LiPF6 in a carbonate blend with 1% DTD and 2%VC.[,]

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说明
价格

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery
Xuecheng L, et al.
Ionics, 20, 795-801 (2014)
Comparative study of 1,3-propane sultone, prop-1-ene-1,3-sultone and ethylene sulfate as film-forming additives for sodium ion batteries
Zhang Q, et al.
Journal of Power Sources, 541, 231726-231726 (2022)
Effect of Sulfate Electrolyte Additives on LiNi1/3Mn1/3Co1/3O2/Graphite Pouch Cell Lifetime: Correlation between XPS Surface Studies and Electrochemical Test Results
Madec L, et al.
The Journal of Physical Chemistry C, 118, 29608-29622 (2014)
A Wide Range of Testing Results on an Excellent Lithium-Ion Cell Chemistry to be used as Benchmarks for New Battery Technologies
Jessie E, et al.
Journal of the Electrochemical Society, 166, A3031-A3031 (2019)
Optimizing Electrolyte Additive Loadings in NMC532/Graphite Cells: Vinylene Carbonate and Ethylene Sulfate
Taskovic T, et al.
Journal of the Electrochemical Society, 168, 010514-010514 (2021)

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