所有图片(2)
About This Item
经验公式（希尔记法）:
C12H18O6
CAS号:
分子量:
258.27
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
98%
旋光性
[α]20/D −120.9°, c = 1 in chloroform
环保替代产品特性
Catalysis
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mp
102-104 °C (lit.)
环保替代产品分类
, Aligned
SMILES字符串
CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1
InChI
1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1
InChI key
IVWWFWFVSWOTLP-RWYTXXIDSA-N
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一般描述
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
应用
Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.
An Efficient Catalytic Asymmetric Epoxidation Method
Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor
An Efficient Catalytic Asymmetric Epoxidation Method
Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor
This organocatalyst is able to epoxidize trans alkenes and certain cis alkenes with good to excellent yields and selectivities.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Yian Shi
Accounts of chemical research, 37(8), 488-496 (2004-08-18)
Chiral ketones have been shown to be effective organocatalysts for asymmetric epoxidation of olefins with broad substrate scope. High enantioselectivity has been obtained for a wide variety of trans and trisubstituted olefins, as well as a number of cis olefins
Tu, Y. et al.
Journal of the American Chemical Society, 118, 9806-9806 (1996)
Frohn, M.; Shi, Y.
Synthesis, 1979-1979 (2000)
Wang, Z.-X. et al.
Journal of the American Chemical Society, 119, 11224-11224 (1997)
Shu, L.; Shi, Y.
Tetrahedron, 57, 5213-5213 (2001)
商品
Catalytic asymmetric epoxidation of alkenes has been the focus of many research efforts over the past two decades, the best known methods probably being those developed by Sharpless and Jacobsen-Katsuki.
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